公开(公告)号：JPH11322585A

公开(公告)日：1999-11-24

申请号：JP7868099

申请日：1999-03-23

Applicant: BASF AG

Inventor： KOTHRADE STEPHAN DR ,  BERNDL GUNTHER ,  SIMON DIRK ,  SANNER AXEL DR

IPC: A23L33/00 ,  A61K9/20 ,  A61K9/22 ,  A61K47/32 ,  A61K47/34 ,  C08F279/02 ,  C08L51/04

Abstract: PROBLEM TO BE SOLVED: To produce the subject dosage form producible by melt extrusion and capable of slowly releasing an agent by using a water swellable graft copolymer as a high-molecular weight binder. SOLUTION: When (A) at least one kind of a high-molecular weight binder, (B) at least one kind of agent and, as necessary, (C) a usual additive are mixed and formed under the formation of a plastic mixture, a water swellable graft copolymer or a mixture thereof is used as the ingredient A. The amounts of the formulated ingredients A and B based on the total weight of the dosage form are preferably 10-100 wt.%, more preferably 40-99.9 wt.% of the ingredient A and preferably 0-90 wt.%, more preferably 0.1-60 wt.% of the ingredient B.

公开(公告)号：JPH1179957A

公开(公告)日：1999-03-23

申请号：JP20633598

申请日：1998-07-22

Applicant: BASF AG

Inventor： DIEING REINHOLD DR ,  HOESSEL PETER DR ,  KOTHRADE STEPHAN DR ,  SANNER AXEL DR ,  ZEITZ KATRIN DR ,  RAUBENHEIMER HANS-JUERGEN ,  SCHEHLMANN VOLKER DR

IPC: A61K8/00 ,  A61K8/49 ,  A61K8/81 ,  A61Q5/00 ,  A61Q5/02 ,  A61Q5/12 ,  A61K7/075 ,  A61K7/06

Abstract: PROBLEM TO BE SOLVED: To use a polymer obtained by the radical copolymerization of a specific monomer mixture composition containing a quaternizable monomer as a conditioning agent in a hair cosmetic composition. SOLUTION: The use of a polymer obtained by the radical copolymerization of a monomer mixture comprising (A) 1-99.99 wt.% of a cationic monomer or a quaternizable monomer [preferably an N-vinylimidazole derivative of the formula (R -R are each H, a 1-4C alkyl or the like)], (B) 0-98.99 wt. % of a water-soluble monomer (preferably N-vinylpyrrolidone), (C) 0-50 wt.% of a radically copolymerizable monomer (e.g. N-t-butylacrylamide) and (D) 0.01-10 wt.% of another bifunctional or multifunctional radically copolymerizable monomer (e.g. tripropylene glycol diacrylate) and further quaternizing the obtained polymer, when the monomer A is not quaternized, as a conditioning agent.

公开(公告)号：JPH10314571A

公开(公告)日：1998-12-02

申请号：JP12341798

申请日：1998-05-06

Applicant: BASF AG

Inventor： KOTHRADE STEPHAN DR ,  MEFFERT HELMUT DR ,  BERNDL GUNTHER DR ,  SANNER AXEL DR ,  STEIN STEFAN DR ,  SCHEHLMANN VOLKER DR ,  RUCHATZ FOLKER DR

IPC: A61K8/72 ,  A61K8/00 ,  A61K8/81 ,  A61K47/14 ,  A61K47/30 ,  A61K47/32 ,  A61Q19/00 ,  B01F17/32 ,  B01F17/52 ,  A61K7/00 ,  A61K7/48

Abstract: PROBLEM TO BE SOLVED: To prepare a solubilization agent for an insoluble action substance. SOLUTION: A copolymer composed of monomers selected out of following items or a mixture of the monomers of 1-40 molar% is used in a prepared material of a water-insoluble substance, and the items are: A) N-vinylpyrrolidone of 60-99% and B) Following groups: b1) monoethylene unsaturated C3 -C8 - carboxylic acid of C8 -C30 -alkylester b2) acrylic acid or methacrylic acid N,N- dialkyl-allyl having C8 -C18 alkyl- or N,N-dialkyl-substituted amide, or b3) aliphatic C8 -C30 -carboxylic acid vinylester.

公开(公告)号：JPH10292022A

公开(公告)日：1998-11-04

申请号：JP9612298

申请日：1998-04-08

Applicant: BASF AG

Inventor： SANNER AXEL DR ,  ZEITZ KATRIN DR ,  LIESKE ANTJE ,  JAEGER WERNER DR

IPC: A61K47/30 ,  A61K8/72 ,  A61K8/86 ,  A61K8/90 ,  A61K9/107 ,  A61K47/32 ,  A61Q5/12 ,  A61Q19/00 ,  B01F17/00 ,  B01F17/52 ,  C08F20/34 ,  C08F26/02 ,  C08F226/02 ,  C08F283/06 ,  C08F293/00 ,  C08G65/00 ,  C08L71/02 ,  C11D1/62 ,  A61K7/00

Abstract: PROBLEM TO BE SOLVED: To provide a block copolymer having excellent solubilizing capacity and stability upon dilution of the substance to be solubilized, which copolymer is a block copolymer having a structure: A-B-A (wherein A is a polyethylene oxide block, and B is a polymer comprising an olefinically unsaturated quat. ammonium compound) and used as a surfactant. SOLUTION: Block A has an average degree of polymerization of 5-100. Block B contains a polymer comprising a quat. ammonium compound (monomer I) represented by formula (wherein (x) is 5-18; R and R are each a 1-5C alkyl; R is a 1-5C alkyl or a hydroxyalkyl; and X is a halide, acetate or metasulfate ion) or contains a mixture of monomer II represented by formula II (wherein R is Cn H2n+1 ; (n) is 5-18; and X is as defined in formula I) and monomer III represented by formula III (wherein R and R are each a 1-3C alkyl or a 1-3C hydroxyalkyl; and X is as defined in formula I) in a ratio of III to II of 1:20 to 20:1.

公开(公告)号：JPH1077345A

公开(公告)日：1998-03-24

申请号：JP20594097

申请日：1997-07-31

Applicant: BASF AG

Inventor： NGUYEN KIM SON DR ,  SANNER AXEL DR ,  HOESSEL PETER DR ,  KRONER MATTHIAS DR

IPC: A61K8/00 ,  A61K8/04 ,  A61K8/34 ,  A61K8/41 ,  A61K8/64 ,  A61K8/81 ,  A61K8/88 ,  A61K8/89 ,  A61K8/891 ,  A61Q5/00 ,  A61Q5/02 ,  A61Q5/12 ,  C08G73/10 ,  A61K7/06

Abstract: PROBLEM TO BE SOLVED: To obtain the subject new polymer useful as a hair-conditioning agent having good biodegradability, conditioning properties, etc., by reacting a polysuccinimide or a polyaspartic acid with a specific amine mixture. SOLUTION: This water-soluble and/or dispersible polyaspartic acid derivative, its salt or its quaternarized product is composed of a unit of the formula I [x1 +x2 +y1 +y2 +z=100; x1 +x2 is 30-99.9; y1 +y2 is 0.1-70; (z) is 0-20; A is a primary to tertiary alkylamine having a 2-6C alkyl and/or a cyclic diamine of the formula II ((n) and (o) are each 1-5; X is NR ; R is H or an alkyl), etc.; B is an amine of the formula III (R is H or a hydrocarbon group of a saturated or an unsaturated fatty acid; Y is CH2 , NH, etc.; (p) is 1-23; R and R are each H, a hydroxyalkyl, etc.); C is a residue obtained by eliminating amine hydrogen from the amine A having primary or secondary amino group; D is a residue obtained by eliminating amino hydrogen from the amine B having primary or secondary amino group].

公开(公告)号：JP2001240512A

公开(公告)日：2001-09-04

申请号：JP2001005577

申请日：2001-01-12

Applicant: BASF AG

Inventor： WITTELER HELMUT ,  BLUM RAINER ,  HOESSEL PETER DR ,  SANNER AXEL DR ,  SCHWALM REINHOLD ,  DAUSCH WILMA M ,  JAWOREK THOMAS ,  KOENIGER RAINER DR

IPC: A61K8/72 ,  A61K8/00 ,  A61K8/02 ,  A61K8/06 ,  A61K8/81 ,  A61K8/86 ,  A61K8/89 ,  A61K8/891 ,  A61K31/765 ,  A61K41/00 ,  A61Q1/00 ,  A61Q1/02 ,  A61Q1/10 ,  A61Q3/00 ,  A61Q3/02 ,  A61Q5/00 ,  A61Q5/02 ,  A61Q5/04 ,  A61Q5/06 ,  A61Q5/10 ,  A61Q5/12 ,  A61Q7/00 ,  A61Q17/04 ,  A61Q19/00 ,  A61Q19/10 ,  C08F290/00 ,  C08F291/00 ,  C08F299/00 ,  C08J3/28 ,  C11D3/20 ,  A61K7/00 ,  A61K7/02 ,  A61K7/032 ,  A61K7/04 ,  A61K7/06 ,  A61K7/075 ,  A61K7/08 ,  A61K7/09 ,  A61K7/13 ,  A61K7/42 ,  A61K7/48

Abstract: PROBLEM TO BE SOLVED: To provide a processing method of cosmetic composition which makes it possible to improve trimming hair of head and skin. SOLUTION: The process by near-infrared radiation (NIR-radiation) prior to, during or after applying the cosmetic composition is provided.

公开(公告)号：JP2001097832A

公开(公告)日：2001-04-10

申请号：JP2000246452

申请日：2000-08-15

Applicant: BASF AG

Inventor： POTTHOFF-KARL BIRGIT DR ,  SPERLING-VIETMEIER KARIN ,  SANNER AXEL DR

IPC: A61K8/00 ,  A61K8/81 ,  A61Q5/00 ,  A61Q5/06 ,  A61Q5/12 ,  C08F8/32 ,  C08F26/06 ,  C08F220/06 ,  C08F220/34 ,  C08F226/06 ,  C08L33/04 ,  C08L33/08 ,  C08L39/00 ,  C08L39/04 ,  A61K7/11

Abstract: PROBLEM TO BE SOLVED: To obtain a film-forming agent having good compatibility with a hydrocarbon-based propellant and useful for a hair cosmetic capable of simultaneously exhibiting good hair setting actions and low hygroscopicity. SOLUTION: This hair setting agent and hairdressing comprise a polymer based on N-vinylcaprolactam as a film-forming agent. The polymer is composed of 35-75 wt.% of group IV of the N-vinylcaprolactam monomer (monomer A), 25-65 wt.% of a mixture of 20-60 pts.wt. of a monomer D with acrylic acid or methacrylic acid (monomer F) and 0-4 wt.% of other radically polymerizable monomers E or 35-80 wt.% of group V of the N-vinylcaprolactam (monomer A), 20-65 wt.% of a mixture of 15-50 pts.wt. of the monomer D with 5-15 pts.wt. of an alkyl acrylate or an alkyl methacrylate monomer (monomer G) having 1-4 carbon atoms in the alkyl group and further amino group unsubstituted or substituted with a 1-4C alkyl group and 0-4 pts.wt. of the other radically polymerizable monomers E. The existing carboxyl groups of the polymer are partially or wholly neutralized with an amine. The polymer contained in the hair setting agent and hairdressing is excellent in compatibility with a nonpolar propellant and exhibits good hair setting actions and curl retention and low water absorptivity.

公开(公告)号：JP2000178311A

公开(公告)日：2000-06-27

申请号：JP35418699

申请日：1999-12-14

Applicant: BASF AG

Inventor： ANGEL MAXIMILIAN DR ,  KOLTER KARL DR ,  SANNER AXEL DR

IPC: A61K9/32 ,  C08F2/16 ,  C08F2/22 ,  C08F2/38 ,  C08F20/10 ,  C08F220/14 ,  C08F220/18

Abstract: PROBLEM TO BE SOLVED: To obtain a polymer dispersion having a low monomer content and excellent storage stability by adjusting the pH of a starting aqueous dispersion by adding at least two basic reagents thereto in a plurality of stages in the course of polymerizing a free-radical-polymerizable ethylenically unsaturated monomer in an aqueous system in the presence of a polymerization initiator. SOLUTION: At least one free-radical-polymerizable ethylenically unsaturated monomer is polymerized in the presence of an acidic polymerization initiator in an aqueous system whose pH has been adjusted at a constant value in the range of 1-7.5 by the addition of a reagent 1 being a salt of an acid selected from the group consisting of carbonic acid, boric acid, acetic acid, citric acid, and phosphoric acid. After the polymerization initiator is consumed, the polymerization is continued in the presence of a redox catalyst, and reagent 1 is further added to the aqueous dispersion to buffer it. The aqueous dispersion is adjusted to a pH of 6-10 by the addition of a reagent 2 being a base selected from the group consisting of an alkali (alkaline earth) metal hydroxide, ammonia, and a primary to tertiary amine to obtain an aqueous polymer dispersion having a residual monomer content of 100 ppm or below.

公开(公告)号：JPH11310618A

公开(公告)日：1999-11-09

申请号：JP7240899

申请日：1999-03-17

Applicant: BASF AG

Inventor： MEFFERT HELMUT DR ,  SANNER AXEL DR ,  BERNDL GUNTHER ,  RUCHATZ FOLKER DR ,  KOLTER KARL DR ,  BAUER KURT HEINZ

IPC: A61K8/63 ,  A61K9/00 ,  A61K9/107 ,  A61K9/20 ,  A61K9/48 ,  A61K47/32 ,  C08F220/04 ,  A61K7/00

Abstract: PROBLEM TO BE SOLVED: To obtain a solubilizing agent having a sufficient solubility and high solubilizing activities in water, and capable of being applied to medicines, cosmetics and foods. SOLUTION: This use is the one of copolymers comprising (a) 82-99.9 mol.% of at least one monoethylenically unsaturated a 3-8C carboxylic acid, (b) 0.1-18 mol.% of at least one monomer selected from the group of (b1 ) N-(8-30C alkyl)- substituted amides of monoethylenically unsaturated 3-8C carboxylic acids, (b2 ) N,N-(8-30C dialkyl)-substituted amides of monoethylenically unsaturated 3-8C carboxylic acids and (b3 ) 8-30C alkyl esters of monoethylenically unsaturated 3-8C carboxylic acids, and (c) 0-17.9 mol.% of at least one monomer selected from the group of (c1 ) vinyl esters of aliphatic 8-30C carboxylic acids and (c2 ) 8-30C alkylvinyl ethers, in which the mol.% data for the individual components adding up to 100%, as a solubilizer.

公开(公告)号：JPH11240921A

公开(公告)日：1999-09-07

申请号：JP33546698

申请日：1998-11-26

Applicant: BASF AG

Inventor： DIEING REINHOLD DR ,  FAUL DIETER ,  RAUBENHEIMER HANS-JUERGEN ,  SANNER AXEL DR

IPC: A61K8/72 ,  A61K8/00 ,  A61K8/02 ,  A61K8/81 ,  A61Q5/06 ,  A61Q11/00 ,  A61Q19/10 ,  C08F2/44 ,  C08F8/12 ,  C08F8/14 ,  C08F216/18 ,  C08F222/06 ,  C08F261/06 ,  C08F267/04 ,  C08F269/00 ,  A61K7/00 ,  A61K7/11 ,  A61K7/16

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a high molecular weight polymer by carrying out a radical solution polymerization of maleic anhydride and an alkyl vinyl ether. SOLUTION: Maleic anhydride and an alkyl vinyl ether (e.g. methyl vinyl ether) is subjected to a radical solution polymerization in the presence of 5-100 wt.% copolymer of the maleic anhydride and the alkyl vinyl ether having 100,000-10,000,000 dalton molecular weight based on the total amount of the monomers to be polymerized, preferably at 40-70 deg.C. The alkyl group of the alkyl vinyl ether has 1-8C. 2, 2'-Azobis(isobutyronitrile), 2,2'-azobis(2,4- dimethylvaleronitrile) or the like is usable as a polymerization initiator. The reaction is preferably carried out in a state in which the copolymer of the maleic anhydride and the alkyl vinyl ether is dissolved in a solvent and present in a vessel.