公开(公告)号：HUT77249A

公开(公告)日：1998-03-02

申请号：HU9701898

申请日：1995-12-16

Applicant: BASF AG

Inventor： FLICK KLEMENS ,  MELDER JOHANN-PETER ,  SCHNURR WERNER ,  VICARI MAXIMILIAN ,  WULFF-DOERING JOACHIM

IPC: B01J25/00 ,  B01J25/02 ,  B01J37/00 ,  C07B31/00 ,  C07C253/30

Abstract: A hydrogenation catalyst based on an alloy of aluminum and of a transition metal is prepared by preparing a kneaded material from the alloy and an assistant, converting the kneaded material into moldings, calcining the moldings and treating the calcined moldings with an alkali metal hydroxide, by a process in which the assistant used is (a) polyvinyl alcohol and water or (b) stearic acid, and the catalyst prepared according to the invention is used for hydrogenation and hydrogenolysis, in particular the partial hydrogenation of aliphatic alpha,omega-dinitriles to aliphatic alpha,omega-aminonitriles.

公开(公告)号：AT231140T

公开(公告)日：2003-02-15

申请号：AT97929276

申请日：1997-06-24

Applicant: BASF AG

Inventor： MASSONNE KLEMENS ,  BECKER RAINER ,  REIF WOLFGANG ,  WULFF-DOERING JOACHIM

IPC: C07B61/00 ,  C07D307/88

Abstract: PCT No. PCT/EP97/03303 Sec. 371 Date Jan. 7, 1999 Sec. 102(e) Date Jan. 7, 1999 PCT Filed Jun. 24, 1997 PCT Pub. No. WO98/01438 PCT Pub. Date Jan. 15, 1998The disclosure is a process for preparing a phthalide of the general formula I where R1, R2, R3 and R4 are each independently of the others hydrogen, C1-C4-alkyl or C1-C4-alkoxy, by hydrogenation of a phthalic anhydride of the general formula II where R1, R2, R3 and R4 are each as defined above, with the aid of a hydrogenation catalyst, which comprises performing the hydrogenation with the aid of a nickel catalyst doped with metals of subgroup 1, subgroup 6 and/or subgroup 7 of the Periodic Table.

公开(公告)号：NO20024648D0

公开(公告)日：2002-09-27

申请号：NO20024648

申请日：2002-09-27

Applicant: BASF AG

Inventor： ARNOLD HEIKO ,  ERDBRUEGGER CRISTINA FREIRE ,  HEIDEMANN THOMAS ,  MEYER GERALD ,  UNVERRICHT SIGNE ,  FRENZEL ANDREA ,  WULFF-DOERING JOACHIM ,  ANSMANN ANDREAS

IPC: B01J35/06 ,  B01J23/42 ,  B01J23/44 ,  B01J23/48 ,  B01J23/50 ,  B01J23/70 ,  B01J23/755 ,  B01J37/02 ,  C07B61/00 ,  C07C5/02 ,  C07C5/03 ,  C07C5/08 ,  C07C7/163 ,  C07C7/167 ,  C07C11/04 ,  C07C11/06 ,  C07C11/08 ,  B01J

Abstract: In a coated catalyst having a core and at least one shell surrounding the core, the core is made up of an inert support material, the shell or shells is/are made up of a porous support substance, with the shell being attached physically to the core, and a catalytically active metal selected from the group consisting of the metals of the 10th and 11th groups of the Periodic Table of the Elements is present in finely divided form or a precursor of the catalytically active metal is present in uniformly distributed form in the shell or shells. The coated catalyst of the present invention is suitable for the reduction of unsaturated hydrocarbons. Here, better selectivities than in the case of previously known coated catalysts can be achieved. A process for producing the coated catalyst is also described.

公开(公告)号：DE59803695D1

公开(公告)日：2002-05-16

申请号：DE59803695

申请日：1998-06-16

Applicant: BASF AG

Inventor： HEINEKE DANIEL ,  DINGERDISSEN UWE ,  WULFF-DOERING JOACHIM ,  HESSE MICHAEL

IPC: C07B61/00 ,  C07C33/26 ,  C07C37/00 ,  C07C37/055 ,  B01J23/44 ,  C07C37/06 ,  C07C37/07 ,  C07C37/50 ,  C07C39/08 ,  C07C41/18 ,  C07C41/28 ,  C07C43/205 ,  C07C43/23

Abstract: Preparation of catechol ether derivatives of formula (Ia) comprises dehydrogenation of 2-hydroxycyclohexanone-dialkyl-ketal derivatives of formula (II) or 2-alkoxycyclohexanone derivatives of formula (III) in the presence of a palladium/zirconium oxide catalyst in the gas phase, and preparation of catechol derivatives of formula (Ia) comprises the above conditions, but in the presence of water. R1, R2 = H or 1-8C hydrocarbon; and R3 = 1-8C hydrocarbon.

公开(公告)号：DE10121026A1

公开(公告)日：2002-02-07

申请号：DE10121026

申请日：2001-04-28

Applicant: BASF AG

Inventor： MERGER MARTIN ,  GERLACH TILL ,  SCHWAB EKKEHARD ,  WULFF-DOERING JOACHIM ,  MUHLER MARTIN ,  HAGEN VOLKER

IPC: B01J21/06 ,  B01J23/10 ,  C07B61/00 ,  C07C45/41 ,  C07C47/02 ,  C07C47/11 ,  C07C221/00 ,  C07C223/02 ,  C07B41/06 ,  C07C47/32 ,  C07C223/00

Abstract: Synthesis of aldehyde (I) involves reacting carboxylic acid (II) or its ester with hydrogen and water in gaseous phase, in the presence of a catalyst containing at least 60-99.9 weight% (wt.%) of zirconium oxide and 20 wt.% or less of lanthanides as catalyst active ingredients. Synthesis of aldehyde of formula (I) involves reacting carboxylic acid of formula (II) or its ester with hydrogen and water in the presence of a catalyst containing at least 60-99.9 wt.% of zirconium oxide and 20 wt.% or less of lanthanides as catalyst active ingredients. R , R , R , R = hydrogen, 1-6C alkyl, 3-8C cycloalkyl, aryl, 7-12C alkylphenyl or 7-12C phenylalkyl, preferably R , R together form 3-7C alicyclic ring, and preferably R , R = 1-4C alkoxy, phenoxy, methylamino, dimethylamino or halogen, more preferably R = hydroxy or amino.

公开(公告)号：DE10014646A1

公开(公告)日：2001-09-27

申请号：DE10014646

申请日：2000-03-24

Applicant: BASF AG

Inventor： FISCHER ROLF ,  PINKOS ROLF ,  SCHUNK STEFAN ,  WULFF-DOERING JOACHIM

IPC: B01J21/18 ,  B01J23/36 ,  B01J23/656 ,  B01J23/889 ,  C07B61/00 ,  C07C29/136 ,  C07C29/149 ,  C07C31/20 ,  C07C31/27 ,  C07C31/133

Abstract: A catalyst (I) comprises 0.01-50 wt.% rhenium and 0-20 wt.% of an additional metal comprising Zn, Cu, Ag, Au, Ni, Fe, Cr or V on an oxidatively pretreated activated carbon support. An independent claim is included for production of alcohols by catalytic hydrogenation of carbonyl compounds by means of a catalyst (I).

公开(公告)号：ES2158423T3

公开(公告)日：2001-09-01

申请号：ES97118631

申请日：1997-10-27

Applicant: BASF AG

Inventor： WULFF-DOERING JOACHIM ,  MELDER JOHANN-PETER ,  SCHULZ GERHARD ,  VOIT GUIDO ,  GUTSCHOVEN FRANK ,  HARDER WOLFGANG

IPC: B01J23/89 ,  C07B61/00 ,  C07C209/02 ,  C07C209/14 ,  C07C209/16 ,  C07C209/26 ,  C07C211/10 ,  C07C211/13 ,  C07C213/02 ,  C07C215/14

Abstract: Catalysts contain, on a porous metal oxide support, 0.1-6 wt% cobalt, nickel or a mixture, 0.001-25 wt% ruthenium, 0-10 wt% copper and 0-5 wt% promoter(s) of iron, rhodium, palladium, platinum, iridium, osmium, silver, gold, chromium, molybdenum, tungsten, rhenium zinc, cadmium, lead, manganese, tin, lithium, sodium, potassium, rubidium, caesium, phosphorus, arsenic, antimony, bismuth, tellurium or thallium. Also claimed are: (i) a process for the production of catalysts, by impregnating the support with the metals and promoters or their compounds, drying and calcining, and reducing the calcined catalyst in a stream of hydrogen, and (ii) a process for the production of amination products by reacting alkylene oxides, alcohol, aldehyde or ketones with ammonia or prim. or sec. amines in presence of free hydrogen and catalyst.

公开(公告)号：CZ288323B6

公开(公告)日：2001-05-16

申请号：CZ197597

申请日：1995-12-16

Applicant: BASF AG

Inventor： VICARI MAXIMILIAN ,  FLICK KLEMENS ,  MELDER JOHANN-PETER ,  SCHNURR WERNER ,  WULFF-DOERING JOACHIM

IPC: B01J25/00 ,  B01J25/02 ,  B01J37/00 ,  C07B31/00 ,  C07C253/30

Abstract: The proposed process for preparing a hydrogenation catalyst based on aluminium alloy and a transient metal is characterized by preparation of a kneading material from the alloy and an auxiliary agent, the kneading material is then formed to shaped bodies, the shaped bodies are subjected to calcination and the calcined shaped bodies are then treated with an alkali metal hydroxide, whereby the auxiliary agent is represented by (a) polyvinyl alcohol and water or (b) stearic acid. The catalyst is intended for hydrogenation and hydrogenolysis, particularly a partial hydrogenation of aliphatic alpha, omega-dinitriles to aliphatic alpha, omega-aminonitriles.

公开(公告)号：DE19942895A1

公开(公告)日：2001-03-15

申请号：DE19942895

申请日：1999-09-08

Applicant: BASF AG

Inventor： HUBER SYLVIA ,  SPRAGUE MICHAEL JOLYON ,  BREITSCHEIDEL BORIS ,  WULFF-DOERING JOACHIM ,  HESSE MICHAEL ,  PINKOS ROLF ,  LIANG SHELUE ,  KUMBERGER OTTO ,  WALTER MARC

IPC: B01J23/80 ,  C07B61/00 ,  C07C29/149 ,  C07C31/04 ,  C07C31/20 ,  C07C29/136 ,  C07B31/00

Abstract: The invention relates to a method for hydrogenating an organic compound which has at least one carbonyl group. According to said method, the organic compound is brought into contact with a shaped body in the presence of hydrogen, said shaped body being produced according to a method in which: (i) an oxidic material containing copper oxide, zinc oxide and aluminium oxide is prepared; (ii) powder-form metallic copper or powder-form cement or a mixture thereof is added to said oxidic material; and (iii) the mixture resulting from (ii) is moulded into a shaped body.

公开(公告)号：DE19823835A1

公开(公告)日：1999-12-02

申请号：DE19823835

申请日：1998-05-28

Applicant: BASF AG

Inventor： LIANG SHELUE ,  FISCHER ROLF HARTMUTH ,  STEIN FRANK ,  WULFF-DOERING JOACHIM

IPC: B01J23/10 ,  C07B61/00 ,  C07C45/48 ,  C07C49/297 ,  C07C45/54 ,  C07C49/395

Abstract: The invention relates to a method for producing cyclopentanone by reacting adipic esters of formula (I) R1OOC-(CH2)4-COOR2 in which R1 and R2 represent alkyl radicals having 1 to 12 carbon atoms, cycloalkyl radicals having 5 or 6 carbon atoms, alkyl aryl or aryl radicals, and R2 can represent additional hydrogen, in the presence of oxidic catalysts. According to the inventive method, adipic esters of formula (I) are reacted with less than 5 wt.% of secondary products, said products not being adipic esters in the gas phase when in the presence of water, with a carrier gas, and a) 0.01 to 10 wt.% of at least one metal oxide, selected from the first or second main group of the periodic table or from the group of rare-earth metals, is reacted on titanium oxide or zirconium dioxide acting as a catalyst support, or b) 0.01 to 50 wt.% of at least one metal oxide, selected from the second main group of the periodic table, is reacted on zinc oxide acting as a catalyst support.