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公开(公告)号:DE60233897D1
公开(公告)日:2009-11-12
申请号:DE60233897
申请日:2002-12-13
Applicant: BREWER SCIENCE INC
Inventor: DESHPANDE SHREERAM V
IPC: G03C1/76 , C08F8/14 , C08F24/00 , C08F34/02 , C08G59/14 , C08G59/32 , C08G59/42 , C08G59/62 , C08G63/68 , C08G63/91 , C08G65/329 , C09D133/02 , C09D163/00 , C09D167/00 , C09D171/02 , C09D201/02 , G03F7/00 , G03F7/09
Abstract: New polymers and new anti-reflective compositions containing such polymers are provided. The compositions comprise a polymer (e.g., epoxy cresol novolac resins) bonded with a chromophore (4-hydroxybenzoic acid, trimellitic anhydride). The inventive compositions can be applied to substrates (e.g., silicon wafers) to form anti-reflective coating layers having high etch rates which minimize or prevent reflection during subsequent photoresist exposure and developing.
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公开(公告)号:AU2003263955A1
公开(公告)日:2004-02-16
申请号:AU2003263955
申请日:2003-07-28
Applicant: BREWER SCIENCE INC
Inventor: GUERRERO DOUGLAS J
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公开(公告)号:AU2003247629A1
公开(公告)日:2004-01-06
申请号:AU2003247629
申请日:2003-06-24
Applicant: BREWER SCIENCE INC
Inventor: NEEF CHARLES J , KRISHNAMURTHY VANDANA
Abstract: Anti-reflective compositions and methods of using these compositions to form circuits are provided. The compositions comprise a polymer dissolved or dispersed in a solvent system. In a preferred embodiment, the polymers include a light-attenuating moiety having a structure selected from the group consisting of:where:each of X and Y is individually selected from the group consisting of electron withdrawing groups;R is selected from the group consisting of alkyls and aryls; andR is selected from the group consisting of hydrogen and alkyls.The resulting compositions are spin bowl compatible (i.e., they do not crosslink prior to the bake stages of the microlithographic processes or during storage at room temperature), are wet developable, and have superior optical properties.
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34.
公开(公告)号:AU2003223582A8
公开(公告)日:2003-10-27
申请号:AU2003223582
申请日:2003-04-11
Applicant: BREWER SCIENCE INC
Inventor: SHIH WU-SHENG , SABNIS RAM W
IPC: C23C14/12 , G02B1/11 , G03F7/09 , H01L21/027 , G03F7/30
Abstract: An improved method for applying polymeric antireflective coatings to substrate surfaces and the resulting precursor structures are provided. Broadly, the methods comprise plasma enhanced chemical vapor depositing (PECVD) a polymer on the substrate surfaces. The most preferred starting monomers are 4-fluorostyrene, 2,3,4,5,6-pentafluorostyrene, and allylpentafluorobenzene. The PECVD processes comprise subjecting the monomers to sufficient electric current and pressure so as to cause the monomers to sublime to form a vapor which is then changed to the plasma state by application of an electric current. The vaporized monomers are subsequently polymerized onto a substrate surface in a deposition chamber. The inventive methods are useful for providing highly conformal antireflective coatings on large surface substrates having super submicron (0.25 mum or smaller) features. The process provides a much faster deposition rate than conventional chemical vapor deposition (CVD) methods, is environmentally friendly, and is economical.
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公开(公告)号:AU2003217804A8
公开(公告)日:2003-09-09
申请号:AU2003217804
申请日:2003-02-25
Applicant: BREWER SCIENCE INC
Inventor: DAFFRON MARK G , SHIH WU-SHENG , SNOOK JULIET ANN MINZEY , LAMB JAMES E
IPC: G03F7/11 , B81C1/00 , G03F7/00 , G03F7/09 , G03F7/095 , H01L21/027 , H01L21/308 , H01L21/3105 , H01L21/311 , H01L21/3205 , H01L21/44
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公开(公告)号:AU2002361686A1
公开(公告)日:2003-09-02
申请号:AU2002361686
申请日:2002-12-13
Applicant: BREWER SCIENCE INC
Inventor: DESHPANDE SHREERAM V
IPC: C08F8/14 , C08G59/14 , C08G59/32 , C08G59/42 , C08G59/62 , C08G63/68 , C08G63/91 , C08G65/329 , C09D133/02 , C09D163/00 , C09D167/00 , C09D171/02 , G03F7/09 , G03C1/76 , C08F34/02 , C08F24/00 , G03C5/00 , G03C1/725 , C08F220/68
Abstract: New polymers and new anti-reflective compositions containing such polymers are provided. The compositions comprise a polymer (e.g., epoxy cresol novolac resins) bonded with a chromophore (4-hydroxybenzoic acid, trimellitic anhydride). The inventive compositions can be applied to substrates (e.g., silicon wafers) to form anti-reflective coating layers having high etch rates which minimize or prevent reflection during subsequent photoresist exposure and developing.
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公开(公告)号:AU2002259251A1
公开(公告)日:2002-12-16
申请号:AU2002259251
申请日:2002-05-14
Applicant: BREWER SCIENCE INC
Inventor: LAMB JAMES E III , HUANG RUNHUI , FLAIM TONY D , PULIGADDA RAMA , SHAO XIE
IPC: H01L21/312 , G03F7/09 , B05D3/02 , C08F8/32 , C08G59/16 , C08F120/32 , C08G59/14 , C08F8/00 , C08F8/14
Abstract: Anti-reflective compositions and methods of using those compositions with low dielectric constant materials are provided. In one embodiment, the compositions include polymers comprising recurring monomers having unreacted epoxide groups. In another embodiment, the polymers further comprise recurring monomers comprising epoxide rings reacted with a light attenuating compound so as to open the ring. The compositions can be applied to dielectric layers so as to minimize or prevent reflection during the dual damascene process while simultaneously blocking via or photoresist poisoning which commonly occurs when organic anti-reflective coatings are applied to low dielectric constant layers.
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公开(公告)号:CA2400157A1
公开(公告)日:2001-08-30
申请号:CA2400157
申请日:2001-02-02
Applicant: BREWER SCIENCE INC
Inventor: SPENCER MARY J , SABNIS RAM W , GUERRERO DOUGLAS , BREWER TERRY
IPC: G03F7/11 , C23C16/46 , G03F7/09 , H01L21/027 , G03C1/76 , G03F7/00 , G11B7/24 , G03C1/492 , G03C1/494
Abstract: An improved method for applying organic antireflective coatings to substrate surfaces and the resulting precursor structures are provided. Broadly, the methods comprise chemical vapor depositing (CVD) an antireflective compound on the substrate surface. In one embodiment, the compound is highly strained (e.g., having a strain energy of at least about 10 kcal/mol) and comprises t wo cyclic moieties joined to one another via a linkage group. The most preferre d monomers are [2.2](1,4)-naphthalenophane and [2.2](9,10)-anthracenophane. Th e CVD processes comprise heating the antireflective compound so as to vaporize it, and then pyrolizing the vaporized compound to form stable diradicals whi ch are subsequently polymerized on a substrate surface in a deposition chamber. The inventive methods are useful for providing highly conformal antireflecti ve coatings on large substrate surfaces having super submicron (0.25.mu.m or smaller) features.
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公开(公告)号:AU7602600A
公开(公告)日:2001-06-12
申请号:AU7602600
申请日:2000-09-20
Applicant: BREWER SCIENCE INC
Inventor: SHAO XIE , COX ROBERT , DESHPANDE SHREERAM V , FLAIM TONY D , PULIGADDA RAMA
Abstract: An improved light attenuating compound for use in the production of microdevices is provided. Broadly, the light attenuating compound is non-aromatic and can be directly incorporated (either physically or chemically) into photolithographic compositions such as bottom anti-reflective coatings (BARC) and contact or via hole fill materials. The preferred non-aromatic compounds of the invention are conjugated aliphatic and alicyclic compounds which greatly enhance the plasma etch rate of the composition. Furthermore, the light attenuating compounds are useful for absorbing light at shorter wavelengths. In one embodiment, the inventive compounds can be polymerized so as to serve as both the polymer binder of the composition as well as the light absorbing constituent.
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公开(公告)号:CA2301020A1
公开(公告)日:1999-04-08
申请号:CA2301020
申请日:1998-09-28
Applicant: BREWER SCIENCE INC
Inventor: GUERRERO DOUGLAS J , KRISHNAMURTHY VANDANA , SHAO XIE , MEADOR JIM D
IPC: G03F7/11 , C08F8/00 , C08F220/32 , C08F283/10 , C09D133/06 , G03F7/09 , G03C1/492 , G03C1/815
Abstract: Anti-reflective coating compositions having improved etchrate, inter alia, are prepared from certain high molecular weight polymers and copolymers, particularly glycidyl methacrylate.
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