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    32.
    发明专利
    未知

    公开(公告)号：NO20012273D0

    公开(公告)日：2001-05-09

    申请号：NO20012273

    申请日：2001-05-09

    Applicant: BASF AG

    Inventor： HEIDEMANN THOMAS ,  HIBST HARTMUT ,  BAUER STEFAN ,  DIETRICH ULF

    IPC: C07D307/89 ,  B01J23/68 ,  B01J35/06 ,  B01J37/02 ,  C01G1/00 ,  C01G31/00 ,  C01G39/00 ,  C07B61/00 ,  C07C51/265 ,  C07C51/31 ,  C01G

    Abstract: A multimetal oxide of the formula I Aga-bMbV2Ox*cH2O,  I where M is a metal selected from the group consisting of Li, Na, K, Rb, Cs, Tl, Mg, Ca, Sr, Ba, Cu, Zn, Cd, Pb, Cr, Au, Al, Fe, Co, Ni and/or Mo, a is from 0.3 to 1.9 and b is from 0 to 0.5, with the proviso that the difference (a−b)≧0.1 and c is from 0 to 20 and x is a number determined by the valence and amount of elements different from oxygen in the formula I, which has a crystal structure giving an X-ray powder diffraction pattern which displays reflections at the lattice spacings d of 15.23±0.6, 12.16±0.4, 10.68±0.3, 3.41±0.04, 3.09±0.04, 3.02±0.04, 2.36±0.04 and 1.80±0.04 Å. Precatalysts and catalysts produced therefrom for the partial oxidation of aromatic hydrocarbons are also provided.

    36.
    发明专利
    未知

    公开(公告)号：DE50308928D1

    公开(公告)日：2008-02-14

    申请号：DE50308928

    申请日：2003-06-27

    Applicant: BASF AG

    Inventor： HEIDEMANN THOMAS ,  SIEBENHAAR URSULA

    IPC: C07C11/08 ,  C07C2/08 ,  C07C2/10

    Abstract: Process for oligomerizing an alkene stream over a solid catalyst comprising sulfur and nickel, in which the oligomerization is carried out in two or more successive catalyst zones and the molar ratio of sulfur to nickel in the first catalyst zone is less than 0.5 and that in the last catalyst zone is 0.5 or more and, in the case of further catalyst zones between the first and last catalyst zones, the molar ratio of sulfur to nickel in each catalyst zone is not less than that in the immediately preceding catalyst zone, based on the main flow direction of the feed stream.

    PRODUCCION DE (CO) AGENTES TENSIOACTIVOS AL HACER REACCIONAR POLIOLES CON OLEFINAS.
    37.
    发明专利
    PRODUCCION DE (CO) AGENTES TENSIOACTIVOS AL HACER REACCIONAR POLIOLES CON OLEFINAS. 未知

    公开(公告)号：MX2007012263A

    公开(公告)日：2007-10-12

    申请号：MX2007012263

    申请日：2006-04-05

    Applicant: BASF AG

    Inventor： HEIDEMANN THOMAS ,  TRILLER MICHAEL ,  STEPHAN J RGEN ,  ROEPER MICHAEL ,  TROPSCH J RGEN

    IPC: C07C43/13 ,  C07C41/06 ,  C08G65/00 ,  C08G65/34 ,  C11D1/66

    Abstract: La invencion se refiere a un metodo para producir eteres de poliolalquilo al hacer reaccionar al menos tres compuestos teniendo funciones de hidroxi con olefinas en presencia de catalizadores acidos a temperaturas de entre 20 - 250 degree C y presiones de entre 0.5 - 10 bar. Las olefinas corresponden a la formula general (I), en donde R1 representa hidrogeno y R2 es radicales de carbono lineales o ramificados teniendo 7 - 28 atomos de carbono, o R1 y R2 respectivamente representan radicales de carbono lineales o ramificados teniendo 1 - 27 atomos de carbono, por lo que el numero de atomos de carbono de R1 y R2 es, a lo mucho, 28. La invencion tambien se refiere a eteres de poliolalquilo que se derivan de compuestos que tienen al menos tres funciones de hidroxi, o todas las funciones de hidroxi hasta que una es reemplazada por un grupo de la formula general (VIII). La invencion se refiere ademas a dichos eteres de polioalquilo como agentes tensioactivos y dichos agentes de lavado y limpieza conteniendo eteres de polioalquilo (ver formulas (I) y (VIII)).

    38.
    发明专利
    未知

    公开(公告)号：BR0315925A

    公开(公告)日：2005-09-20

    申请号：BR0315925

    申请日：2003-10-28

    Applicant: BASF AG

    Inventor： BITTERLICH STEFAN ,  VOSS HARTWIG ,  SCHUCH GUNTER ,  HEIDEMANN THOMAS

    IPC: C07C2/24 ,  C07C7/13 ,  C07C11/02

    Abstract: The present invention relates to a process for preparing oligomers consisting mainly of repeating units derived from 1- or 2-butene from a hydrocarbon stream consisting substantially of branched and linear hydrocarbon compounds having 4 carbon atoms, and comprising olefinic branched and linear hydrocarbon compounds having 4 carbon atoms (C 4 starting stream) by a. in step a), separating the C 4 starting stream into a fraction consisting mainly of linear hydrocarbon compounds having 4 carbon atoms (l-C 4 fraction) and a fraction consisting mainly of branched hydrocarbon compounds having 4 carbon atoms (b-C 4 fraction), by contacting the C 4 starting stream with a membrane which is easier to pass for linear hydrocarbon compounds having 4 carbon atoms than for branched hydrocarbon compounds having 4 carbon atoms, b. in step b), optionally after removing butanes, oligomerizing the olefinic hydrocarbon compounds having 4 carbon atoms present in the l-C 4 fraction, c. in step c), subjecting the olefinic hydrocarbon compounds having 4 carbon atoms present in the b-C 4 fraction to one of the following steps: c1. reaction with methanol to give methyl tert-butyl ether (step c1) c2. hydroformylation to give substantially isovaleraldehyde (step c2) c3. polymerization to polyisobutylene (step c3) c4. dimerization to 2,4,4-trimethyl-1-pentene (step c4) c5. alkylation, substantially to form saturated hydrocarbon compounds having 8 or 9 carbon atoms (step c5).

    PROCESS FOR THE PREPARATION OF ALKYLARYL COMPOUNDS
    39.
    发明专利
    PROCESS FOR THE PREPARATION OF ALKYLARYL COMPOUNDS 未知

    公开(公告)号：CA2544867A1

    公开(公告)日：2005-07-07

    申请号：CA2544867

    申请日：2004-12-17

    Applicant: BASF AG

    Inventor： TROPSCH JUERGEN ,  ROEPER MICHAEL ,  STEPHAN JUERGEN ,  NARBESHUBER THOMAS ,  BOTTKE NILS ,  HEIDEMANN THOMAS ,  STEINBRENNER ULRICH ,  BENFER REGINA

    IPC: C07C303/00 ,  C07C2/66 ,  C07C303/06 ,  C07C309/31 ,  C11D1/22 ,  C11D11/04

    Abstract: The preparation of alkylaryl compounds takes place by a) reaction of a C 4 /C 5 -olefin mixture over a metathesis catalyst to prepare a C 4-8 -olefin mixture comprising 2-pentene, and optional removal of the C 4-8 -olefin mixture, b) removal of from 5 to 100% of the 2-pentene present in stage a) and subsequent reaction over an isomerization catalyst to give a mixture of 2-pentene and 1-pentene which is returned to stage a), c) dimerization of the C 4-8 -olefin mixture obtained in stage b) following removal in the presence of a dimerization catalyst to give a mixture containing C 8-16 -olefins, removal of these C 8-16 -olefins and optional removal of a partial stream thereof, d) reaction of the c 8-16 -olefin mixtures obtained in stage c) or of the partial stream with an aromatic hydrocarbon in the presence of an alkylation catalyst to form alkyl aromatic compounds where, prior to the reaction, 0 to 60% by weight, based on the c 8-16 -olefin mixtures obtained in stage c), of linear olefins may additionally be added, e) optional sulfonation of the alkyl aromatic compounds obtained in stage d) and neutralization to give alkylarylsulfonates, where, prior to the sulfonation, 0 to 60% by weight, based on the alkyl aromatic compounds obtained in stage d), of linear alkylbenzenes may additionally be added if no admixing has taken place in stage d), f) optional mixing of the alkylarylsulfonates obtained in stage e) with 0 to 60% by weight, based on the alkylarylsulfonates obtained in stage e), of linear alkylarylsulfonate, if no admixing has taken place in stages d) and e).

    PROCEDIMIENTO PARA LA OBTENCION DE OLIGOMEROS.
    40.
    发明专利
    PROCEDIMIENTO PARA LA OBTENCION DE OLIGOMEROS. 未知

    公开(公告)号：ES2221644T3

    公开(公告)日：2005-01-01

    申请号：ES01927780

    申请日：2001-03-22

    Applicant: BASF AG

    Inventor： SCHULTZ RALF ,  HEIDEMANN THOMAS ,  SCHWAB PETER ,  ZEHNER PETER

    IPC: B01J19/24 ,  C07B61/00 ,  C07C2/08 ,  C07C2/10 ,  C07C2/24 ,  C07C11/02

    Abstract: Procedimiento para la obtención de oligómeros de alquenos esencialmente no ramificados con 4 a 6 átomos de carbono, partiendo de los alquenos o de una corriente de hidrocarburos que contiene alquenos de este tipo en un catalizador heterogéneo que contiene níquel en un reactor accionado adiabáticamente a temperaturas desde 20 hasta 300ºC y a presiones de 1 a 100 bar, caracterizado porque se elabora una primera corriente parcial de la descarga del reactor a los oligómeros y se reconduce la segunda corriente parcial conjuntamente con alqueno fresco o una corriente de hidrocarburos fresca, que contiene alquenos de este tipo, al reactor.

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