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公开(公告)号:AT360476T
公开(公告)日:2007-05-15
申请号:AT05011988
申请日:2005-06-03
Applicant: BASF AG
Inventor: KASHANI-SHIRAZI NAWID , MILLER CHRISTIAN , HEISSLER HEINRICH-DIETER , MUELLER JOACHIM
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公开(公告)号:DE102005014177A1
公开(公告)日:2006-10-05
申请号:DE102005014177
申请日:2005-03-29
Applicant: BASF AG
Inventor: HILL THOMAS , MILLER CHRISTIAN
Abstract: A process is proposed for obtaining a stream of aliphatic hydrocarbons comprising from 5 to 12 carbon atoms per molecule, with an increased proportion of linear alpha-olefins compared to a feed stream of aliphatic hydrocarbons comprising from 5 to 12 carbon atoms per molecule, with a content of linear alpha-olefins, linear internal olefins and dienes, wherein the feed stream is fed to a first distillation zone D 1 having at least 5 theoretical plates, in which the linear alpha-olefins are removed partly or fully as a component of a vapor stream which additionally also comprises the dienes, and at whose lower end a liquid stream is obtained which has been depleted partly or fully of linear alpha-olefins, the liquid stream from the lower end of the first distillation zone D 1 is introduced into a isomerization unit which is equipped with an isomerization catalyst over which the linear internal olefins are isomerized partly or fully to linear alpha-olefins, and the linear alpha-olefins formed in this way are removed as a component of a vapor stream ascending into the first distillation zone D 1, the vapor stream ascending out of the first distillation zone D 1 enters a selective hydrogenation unit in which at least a portion of the dienes are hydrogenated selectively to olefins over a low-isomerization selective hydrogenation catalyst to obtain a vapor stream which is drawn off, condensed fully or partly and drawn off as a product stream with an increased proportion of linear alpha-olefins compared to the feed stream.
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公开(公告)号:ES2253614T3
公开(公告)日:2006-06-01
申请号:ES03015957
申请日:2003-07-14
Applicant: BASF AG
Inventor: MILLER CHRISTIAN , KAIBEL GERD DR , SIEGEL HARDO DR
Abstract: Procedimiento para la puesta en práctica de una destilación reactiva en presencia de un catalizador heterogéneo, que está suspendido como fase dispersa en el líquido, u descargándose continuamente de la columna una parte de suspensión que contiene catalizador, u tratándose en una etapa de elaboración, y u devolviéndose el catalizador elaborado a la columna al menos parcialmente, caracterizado porque en la zona en la que se encuentra el catalizador en la columna se emplean empaquetaduras estructuradas como elementos de inserción.
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公开(公告)号:DE102004003239A1
公开(公告)日:2005-08-18
申请号:DE102004003239
申请日:2004-01-21
Applicant: BASF AG
Inventor: RUDOLF PETER , MILLER CHRISTIAN , WALSDORFF CHRISTIAN
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公开(公告)号:CA2553041A1
公开(公告)日:2005-08-11
申请号:CA2553041
申请日:2005-01-27
Applicant: BASF AG
Inventor: LUYKEN HERMANN , HADERLEIN GERD , BARTSCH MICHAEL , JUNGKAMP TIM , MILLER CHRISTIAN , SCHEIDEL JENS , BASSLER PETER , BAUMANN ROBERT , SIEGEL WOLFGANG
IPC: C07C253/30 , C07C255/07
Abstract: The invention relates to a method for isomerization of pentene nitrile in an educt flow, wherein isomerization is performed on a homogeneously dissolved catalyst.
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公开(公告)号:DE10359026A1
公开(公告)日:2005-07-21
申请号:DE10359026
申请日:2003-12-15
Applicant: BASF AG
Inventor: DOBLER WALTER , BAHR NICOLAUS , KINDLER ALOIS , MILLER CHRISTIAN , SALDEN AXEL
IPC: C07C45/62 , C07C45/74 , C07D231/12 , C07D231/14 , C07D231/16 , C07D231/18 , C07D231/38 , C07D231/56 , C07D233/54 , C07D235/06 , C07D249/12 , C07D257/04 , C07D311/72 , C07D401/12 , C07D403/12 , C07D409/04 , C07D473/34 , C07C45/72 , C07C49/04 , C07C29/145 , C07C33/025 , C07C33/03
Abstract: The present invention relates to a process for preparing tetrahydrogeranylacetone (tetrahydropseudoionone) by aldol condensation of citral with acetone and subsequent hydrogenation. The invention further relates to the use of thus obtained tetrahydro-geranylacetone for preparing phytol, isophytol, tocopherol and/or tocopherol derivatives. In addition, the invention relates to processes for preparing tocopherols and/or tocopherol derivatives.
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公开(公告)号:AU2003251465A1
公开(公告)日:2004-03-29
申请号:AU2003251465
申请日:2003-07-24
Applicant: BASF AG
Inventor: DOBLER WALTER , KAIBEL GERD , MILLER CHRISTIAN , OOST CARSTEN , STROEZEL MANFRED , HAAKE MATHIAS , AQUILA WERNER
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公开(公告)号:DE10163335A1
公开(公告)日:2003-07-10
申请号:DE10163335
申请日:2001-12-21
Applicant: BASF AG
Inventor: KAIBEL GERD , MILLER CHRISTIAN , KLAS KATRIN , KINDLER ALOIS , AQUILA WERNER , DOBLER WALTER , BREUER KLAUS , POMMER ACHIM , DIRNSTEINER THOMAS
Abstract: Distillation column has a dividing wall which divides it into inflow and extraction sections, and upper and lower column zones. The mixture for distillation comprises a vapor feed which enters between the upper and lower inflow sections, between which the side extraction point removes vapor. The inflow and the extraction zones are offset relative too the dividing wall. The vapor feed rate is equal in all zones of the column. The distillation column has a dividing wall (TW) which divides it into an inflow section (2,4), an extraction section (3,5), and common upper (1) and lower (6) column zones. The mixture for distillation is at least partially a vapor feed (F) which enters between the upper and lower inflow sections, and the side extraction point (B) removes vapor between the upper and lower extraction zones. The cross sectional surfaces of the inflow and the extraction zones are set by an offset in the dividing wall. The F-factor is equal in all the zones of the column, defined as the product of the gas flow speed in m/seconds multiplied with the square root of the gas density in kg/m3.
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公开(公告)号:AU2002358098A1
公开(公告)日:2003-06-17
申请号:AU2002358098
申请日:2002-12-05
Applicant: BASF AG
Inventor: DOBLER WALTER , DIRNSTEINER THOMAS , SIGL MARCUS , JANSEN HELMUT , KAIBEL BJORN , KAIBEL GERD , MILLER CHRISTIAN
IPC: B01D3/26 , B01D3/00 , B01J8/00 , B01J8/02 , B01J8/04 , B01J8/12 , B01J19/24 , B01J19/32 , B01J21/04 , B01J23/10 , B01J35/02 , C07B61/00 , C07C45/72 , C07C45/74 , C07C49/203 , C07C45/28
Abstract: A column is described for carrying out reactive distillations in the presence of a heterogeneous particulate catalyst having an ordered packing or random packings which form intermediate spaces in the column interior, the quotient of the hydraulic diameter for the gas flow through the ordered packing or the random packings and the equivalent diameter of the catalyst particles being in the range from 2 to 20, preferably in the range from 5 to 10, in such a manner that the catalyst particles are introduced into the intermediate spaces, distributed and discharged loose under the action of gravity.
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公开(公告)号:ES2286739T3
公开(公告)日:2007-12-01
申请号:ES05011988
申请日:2005-06-03
Applicant: BASF AG
Inventor: KASHANI-SHIRAZI NAWID , MILLER CHRISTIAN , HEISSLER HEINRICH-DIETER , MULLER JOACHIM
Abstract: Relleno de canales múltiples para la realización de destilaciones reactivas catalizadas de manera heterogénea con canales de catalizador acortados lateralmente en uno o ambos lados al menos parcialmente, ascendiendo este acortamiento a de 1 a 10 veces el diámetro equivalente de las partículas de catalizador que van a introducirse.
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