35.
    发明专利
    未知

    公开(公告)号:BR9709702A

    公开(公告)日:1999-08-10

    申请号:BR9709702

    申请日:1997-05-30

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP97/02821 Sec. 371 Date Dec. 14, 1998 Sec. 102(e) Date Dec. 14, 1998 PCT Filed May 30, 1997 PCT Pub. No. WO97/47386 PCT Pub. Date Dec. 18, 1997An oxidation catalyst based on titanium silicalites or vanadium silicalites having a zeolite structure and containing from 0.01 to 30% by weight of one or more noble metals selected from the group consisting of ruthenium, rhodium, palladium, osmium, iridium, platinum, rhenium, gold and silver has been molded by a compacting shaping process. This oxidation catalyst is used for the preparation of epoxides, in particular propylene oxide, from olefins, hydrogen and oxygen.

    38.
    发明专利
    未知

    公开(公告)号:ES2121477T3

    公开(公告)日:1998-11-16

    申请号:ES96904060

    申请日:1996-02-10

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP96/00578 Sec. 371 Date Aug. 5, 1997 Sec. 102(e) Date Aug. 5, 1997 PCT Filed Feb. 10, 1996 PCT Pub. No. WO96/26198 PCT Pub. Date Aug. 29, 1996Preparation of epoxides from olefins by means of aromatic peroxycarboxylic acids comprises a step A of epoxidizing the olefin and removing the resulting aromatic carboxylic acid from the epoxide, a step B of catalytically hydrogenating the removed aromatic carboxylic acid to the corresponding aromatic aldehyde, and a step C of oxidizing this aldehyde with oxygen or an oxygen-containing gas mixture back to the aromatic peroxycarboxylic acid for re-use for epoxidizing an olefin.

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