Abstract:
Halogenated alcohols used in gas phase polymerization of ethylene in combination with a Ti based catalyst component and aluminum alkyls as co-catalyst allows to efficiently suppress ethane formation and to simultaneously increase the polymerization activity.
Abstract:
A porous solid adduct comprising magnesium chloride and ethanol characterized by a specific relation between content of alcohol, average pore radius and amount of porosity deriving from pores with radius comprised between 100 and 1000 nm is provided to generate catalyst components which in turn generate polyolefins endowed with higher porosity.
Abstract:
A polyolefin composition comprising: A) from 90.0 wt% to 99.0 wt%; of a copolymer of propylene with ethylene wherein: i) the content of ethylene derived units comprised between 1.0 wt% and 8.0 wt%; (ii) the melting temperature ranges from 135° C to 155° C; (iii) the melt flow rate (230°C/5 kg.. ISO 1133) ranging from 0.2 g/10min to 3.5 g/10min; (iv) the xylene solubles at 25°C ranges from 10.0 wt% to 4.0wt%; (v) the polydispersity, PI, ranges from 3.0 to 7.0; B) from 1.0 wt% to 10.0 wt%; of a propylene ethylene copolymer containing from 8.0 wt% to 20.0 wt% of ethylene; said copolymer having a MFR (measured at 190°C 2.16 kg of load) comprised between 0.5 g/10 min and 5.0 g/10 min wherein the resulting polyolefin composition has an melt flow rate (230°C/5 kg.. ISO 1133) ranging from 0.2 g/10min to 4.0 g/10min; the sum A+B being 100.
Abstract:
A polyolefin composition comprising: A) from 90.0 wt% to 99.0 wt%; of a copolymer of propylene with ethylene wherein: i) the content of ethylene derived units is comprised between 1.0 wt% and 8.0 wt%; (ii) the melting temperature ranges from 135° C to 155° C; (iii) the melt flow rate (230°C/5 kg.. ISO 1133) ranging from 0.2 g/10min to 3.5 g/10min; (iv) the xylene solubles at 25°C ranges from 20.0 wt% to 4.0wt%; (v) the polydispersity, PI, ranges from 3.0 to 7.0; B) from 1.0 wt% to 10.0 wt%; of a propylene, ethylene copolymer composition comprising: b1) from 12 wt% to 52 wt%; of a propylene homopolymer or a propylene/ethylene copolymer; b2) from 48 wt% to 88 wt% of a propylene ethylene copolymer having a content of ethylene derived units ranging from 15.0 wt% to 42.0 wt%.
Abstract:
A propylene polymer composition comprising: A) from 81 wt% to 91 wt% of a propylene ethylene copolymer containing from 1.0 wt% to 3.5 wt% of ethylene derived units having a fraction soluble in xylene at 25°C comprised between 10 wt% and 3 wt%; and a melt flow rate ranging from 5 to 50 g/10 min; B) from 9 wt% to 19 wt%, of a copolymer of propylene and ethylene with from 21.0 wt% to 31.0 wt% of ethylene derived units; the sum A) + B) being 100; the composition having an melt flow rate ranging from 20 to 35 g/10 min; the xylene soluble fraction at 25°C ranging from 13.0 wt% to 25.0 wt% and the intrinsic viscosity of the fraction soluble in xylene at 25°C ranging from 0.7 dl/g to 1.9 dl/g.
Abstract:
A polypropylene composition for the production of molded articles, such as finished parts for the automotive industry, has melt flow rate (230°C, 2.16 Kg) of at least 25 g /10 min and comprises: (A) 50-95% of a composition having an intrinsic viscosity of the fraction soluble in xylene at 25 °C of 3.0-5.0 dl/g and comprising: (Al) 70-95% of a propylene homopolymer having a Polydispersity Index (PI) of 4.3-10, a fraction insoluble in xylene at 25 °C higher than 90% and a MFR (230°C, 2.16 Kg) of 100- 250 g/10 min; (A2) 5-30% of a copolymer of propylene with 36-44% of ethylene-derived units; (B) optionally up to 45% of a heterophasic propylene polymer, having MFR (230°C, 2.16 Kg) of 10-25 g/10 min, flexural modulus higher than 1400 MPa, and comprising 5-20% of a copolymer rubber component and 80-95% of a matrix propylene polymer component; (C) 2-10% of an ethylene based elastoplastic copolymer; and (D) optionally up to 20% of talc.
Abstract:
A solid catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor of formula (I), where R 1 is selected from C 1 -C 15 hydrocarbon groups, R 2 groups, equal to or different from each other, are hydrogen or R 1 groups which can be fused together to form one or more cycles and A is a bivalent bridging group. The said catalyst components exhibit high activity and stereo specificity in the polymerization of olefins.
Abstract:
Films or sheets comprising a layer of a heterophasic propylene copolymer containing up to 7.0% by weight of ethylene-derived units and comprising: (a) from 80% to 92% by weight of a matrix phase being a propylene homopolymer or a propylene copolymer containing up to 5% by weight of units derived from ethylene and/or an alpha-olefin; and (b) from 8% to 20% by weight of a rubber phase that is an ethylene-propylene copolymer containing from 20% to 60% by weight of ethylene-derived units.
Abstract:
Sterilisable articles for use in healthcare or medical applications, such as blow-fill-seal applications, made of a propylene-ethylene random copolymer show good optical properties also after heat sterilization.
Abstract:
A container comprising a propylene, ethylene, 1-hexene terpolymer wherein in the terpolymer: (i) the content of ethylene derived units ranges from 0.5 wt% to 2.0 wt%; (ii) the content of 1-hexene derived units ranges from 1.5 wt% to 5.5 wt%; (iii) the content of ethylene derived units fulfills the following equation (I); C2