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公开(公告)号:DE19500756A1
公开(公告)日:1996-07-18
申请号:DE19500756
申请日:1995-01-13
Applicant: BASF AG
Inventor: WARZELHAN VOLKER DR , KRONER MATTHIAS DR , HOFMANN JUERGEN , SEELIGER URSULA DR , YAMAMOTO MOTONORI , BAUER PETER
IPC: A01G9/10 , B65D65/46 , C08G69/40 , C08G69/44 , C08G69/48 , C08G73/04 , C08J9/00 , C08L3/02 , C08L77/12 , C08L101/16 , C09J177/12 , C08G81/00 , C08G69/42 , C08G63/685 , C08K5/09 , C08L67/04 , G09F3/00
Abstract: The invention concerns biologically degradable polyester amides Q1 obtainable through reaction of a mixture consisting essentially of the following: (a1) 95-99.9 wt % polyester amide P1 obtainable through reaction of a mixture consisting essentially of: (b1) a mixture consisting essentially of: 35-95 mol % adipic acid or ester-forming derivatives thereof or mixtures thereof, 5-65 mol % terephthalic acid or ester-forming derivatives thereof or mixtures thereof; and 0-5 mol % a compound containing sulphonate groups (the sum of the molar percentages is 100); (b2) a mixture of dihydroxy compounds consisting essentially of: (b21) 99.5-0.5 mol % a dihydroxy compound chosen from the group comprising C2-C6 alkane diols and C5-C10 cycloalkane diols, (b22) 0.5-99.5 mol % an amino C2-C12 alkanol or an amino C5-C10 cycloalkanol, (b23) 0-50 mol a diamino C1-C8 alkane, and (b24) 0-50 mol % a 2,2'-bisoxazoline; (a2) 0.1-5 wt % a divinyl ether C1; and (a3) 0-5 mol % (in relation to components b1 from the production of P1) compound D. The invention also concerns other biologically degradable polymers and thermoplastic moulding materials, a process for manufacturing the same and the use thereof for producing biologically degradable moulded articles and adhesives, and biologically degradable moulded articles obtainable from the polymers or moulding materials according to the invention.
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公开(公告)号:DE4444711A1
公开(公告)日:1996-06-20
申请号:DE4444711
申请日:1994-12-15
Applicant: BASF AG
Inventor: MARCZINKE BERND LOTHAR DR , MUELLER PATRIK DR , KOESSLER LUDWIG , SCHERR GUENTER DR , BROSIUS SIBYLLE DR , GUENTHER ERHARD DR , HOFMANN JUERGEN
IPC: C08K5/3492 , C08L23/10 , C08L51/06 , D01F6/46
Abstract: Plastic materials with a melt flow index 230/2.16 of 0.1-100 g/10 minutes contain: (a1) propylene homopolymer with a melt flow index 230/2.16 of 0.1-100 g/10 minutes, or(a2) statistical copolymer of propylene and 2-10C alkene-1 with a comonomer content of less than 15 wt.%, or (a3) a mixt. of 25-97 wt.% of a copolymer of propylene and 0.1-15 wt.% 2-10C alkene-1 and 3-75 wt.% of another propylene copolymer contg. 15-80 wt.% 2-10C alkene-1 units, or(a4) a mixt. of 25-97 wt.% propylene homopolymer and 3-75 wt.% propylene/2-10C alkene-1 copolymer, with a comonomer content of 15-80 wt.% w.r.t. the second polymer, (b) a propylene or ethylene polymer grafted with 0.1-5 wt.% alpha , beta -unsatd. carboxylic acid or acid deriv., with a melt flow index 230/2.16 of 0.01-400 g/10 minutes, and (c) a nitrogen cpd. of formula (I): R =H, 1-30C alkyl, 2-30C alkyl or alk-1-enyl substd. with O atom(s) and/or amino gps., or a gp. of formula (II):HO-(CHR -CHR )m- (II)R =H, 1-4C alkyl or amino; andm=1-100. Also claimed are: (i) a process for the prodn. of the materials, by reacting components (a)-(c) together at 180-280 deg C and 1-100 bar for a mean residence time of 0.2-10 minutes; and(ii) film, fibres and mouldings made from the materials.
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公开(公告)号:DE4422165A1
公开(公告)日:1996-01-04
申请号:DE4422165
申请日:1994-06-24
Applicant: BASF AG
Inventor: MARCZINKE BERND LOTHAR DR , SCHWAGER HARALD DR , HINGMANN ROLAND DR , HOFMANN JUERGEN , SEELERT STEFAN DR
Abstract: Partly crosslinked plastic materials (A) with a melt flow index 230/2.16 of 0.1-100 g/10 minutes are obtd from: (a1) a polymer contg: (a1.1) 25-97 wt% of a copolymer of propylene with 0.1-15 wt% 2-10C alkene-1, and (a1.2) 3-75 wt% of a copolymer of propylene with 15-80 wt% 2-10C alkene-1; or (a2) a polymer contg: (a2.1) 25-97 wt% propylene homopolymer, and (a2.2) 3-75 wt% copolymer (a1.2) as above; or (a3) a propylene homopolymer with a melt flow index 230/2 of 0.1-100 g/10 minutes; or (a4) a statistical propylene copolymer contg less than 15 wt% 2-10C alkene-1 comonomer; and (b) a cpd of formula: (H2C=CR-COO)nX (I) R = H or 1-4C alkyl; X = 1-30C alkyl or 7-30C aralkyl, opt contg in-chain O and/or N atom(s); and n = 2 or 3; and these materials (A) are obtd by reacting (a1), (a2), (a3) or (a4) with cpd (b) at 180-280 deg C and 1-100 bar for a mean residence time of 0.2-10 minutes. Also claimed are: (i) a process for the prodn of (A) by reacting the above polymers with (b) at 190-260 deg C and 1-60 bar for a mean residence time of 0.2-5 minutes, pref immediately after prodn of the polymer in a mixer connected to the polymerisation reactor; and (ii) films, fibres and mouldings made from (A).
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公开(公告)号:DE4421929A1
公开(公告)日:1996-01-04
申请号:DE4421929
申请日:1994-06-23
Applicant: BASF AG
Inventor: MARCZINKE BERND LOTHAR DR , SCHWAGER HARALD DR , HINGMANN ROLAND , HOFMANN JUERGEN , SEELERT STEFAN DR
Abstract: Partly crosslinked plastic materials (A) with a melt flow index 230/2.16 of 0.1-100 g/10 minutes are obtd from: (a1) a polymer contg: (a1.1) 25-97 wt% of a copolymer of propylene with 0.1-15 wt% 2-10C alkene-1, and (a1.2) 3-75 wt% of a copolymer of propylene with 15-80 wt% 2-10C alkene-1; or (a2) a polymer contg: (a2.1) 25-97 wt% propylene homopolymer, and (a2.2) 3-75 wt% copolymer (a1.2) as above; or (a3) a propylene homopolymer with a melt flow index 230/2 of 0.1-100 g/10 minutes; or (a4) a statistical propylene copolymer contg less than 15 wt% 2-10C alkene-1 comonomer; and (b) a cpd of formula: (H2C=CR-COO)nX (I) R = H or 1-4C alkyl; X = 1-30C alkyl or 7-30C aralkyl, opt contg in-chain O and/or N atom(s); and n = 2 or 3; and these materials (A) are obtd by reacting (a1), (a2), (a3) or (a4) with cpd (b) at 180-280 deg C and 1-100 bar for a mean residence time of 0.2-10 minutes. Also claimed are: (i) a process for the prodn of (A) by reacting the above polymers with (b) at 190-260 deg C and 1-60 bar for a mean residence time of 0.2-5 minutes, pref immediately after prodn of the polymer in a mixer connected to the polymerisation reactor; and (ii) films, fibres and mouldings made from (A).
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公开(公告)号:DE4420784A1
公开(公告)日:1995-12-21
申请号:DE4420784
申请日:1994-06-15
Applicant: BASF AG
Inventor: HEITZ THOMAS DR , KOCH JUERGEN DR , HOFMANN JUERGEN , ARNOLD-MAUER BAERBEL DR , NEUFELD ECKHARD
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公开(公告)号:ES2066265T3
公开(公告)日:1995-03-01
申请号:ES91108290
申请日:1991-05-23
Applicant: BASF AG
Inventor: BAUMGARTNER EHRENFRIED DR , HOFMANN JUERGEN , MOORS RAINER DR , SCHAECH HANSJOERG , BUESCHL RAINER DR , JUNG RUDOLF H DR
IPC: C08F279/04 , C08F279/00 , C08F285/00 , C08F287/00 , C08L51/00
Abstract: Rubber-modified, high-impact acrylonitrile/butadiene/styrene (ABS) moulding compositions, as obtained by polymerisation of styrene and acrylonitrile in the presence of a preformed rubber, dissolved in monomeric styrene and acrylonitrile and optionally a solvent, containing, as rubber, a styrene-butadiene block copolymer and at least one further polymer which is compatible with styrene-butadiene block rubber or its polystyrene component and is incompatible with polystyrene-acrylonitrile.
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公开(公告)号:DE4326774A1
公开(公告)日:1995-02-16
申请号:DE4326774
申请日:1993-08-10
Applicant: BASF AG
Inventor: NEUFELD ECKHARD , ARNOLD-MAUER BAERBEL DR , HOFMANN JUERGEN , HEITZ THOMAS DR , SACHSENWEGER CHRISTOPH DR , WIELAND PETRA
Abstract: In order to prepare polyarylene ether ketones by Friedel-Crafts polycondensation, a reaction mixture comprising A. a monomer system, B. a Lewis acid, C. optionally a Lewis base and D. an inert solvent is polycondensed in two reaction zones and discharged in plug flow from the second reaction zone and formulated. In this process, the reaction mixture is polycondensed in the first reaction zone with stirring to a viscosity of about 2000 mPa.s, transferred into the second reaction zone and discharged therefrom by means of an inert solvent or by means of an inert gas saturated with the solvent under a pressure of from about 6 to 65 bar, preferably even 10 to 25 bar, where the conveying pressure is reduced in at least two steps and the pressure reduction in the first step is at most 20%.
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公开(公告)号:DE59103961D1
公开(公告)日:1995-02-02
申请号:DE59103961
申请日:1991-05-23
Applicant: BASF AG
Inventor: BAUMGARTNER EHRENFRIED DR , HOFMANN JUERGEN , MOORS RAINER DR , SCHAECH HANSJOERG , BUESCHL RAINER DR , JUNG RUDOLF H DR
IPC: C08F279/04 , C08F279/00 , C08F285/00 , C08F287/00 , C08L51/00
Abstract: Rubber-modified, high-impact acrylonitrile/butadiene/styrene (ABS) moulding compositions, as obtained by polymerisation of styrene and acrylonitrile in the presence of a preformed rubber, dissolved in monomeric styrene and acrylonitrile and optionally a solvent, containing, as rubber, a styrene-butadiene block copolymer and at least one further polymer which is compatible with styrene-butadiene block rubber or its polystyrene component and is incompatible with polystyrene-acrylonitrile.
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公开(公告)号:DE4217914A1
公开(公告)日:1993-12-02
申请号:DE4217914
申请日:1992-05-30
Applicant: BASF AG
Inventor: HESSE ANTON DR , HOFMANN JUERGEN , HECKMANN WALTER DR , WARZELHAN VOLKER DR
Abstract: The invention relates to a process for the preparation of a curable moulding composition based on a dispersion of a finely divided ethylene polymer in an unsaturated polyester resin. A melt of the ethylene polymer is distributed uniformly in a melt of an unsaturated polyester in an extruder or stirred reactor.
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公开(公告)号:DE4402394B4
公开(公告)日:2005-02-10
申请号:DE4402394
申请日:1994-01-27
Applicant: BASF AG
Inventor: GUENTHERBERG NORBERT , HOFMANN JUERGEN , OHLIG HILMAR , MAILAHN ELMAR , SEITZ FRIEDRICH , GAUSEPOHL HERMANN , KOCH JUERGEN , DECKERS ANDREAS
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