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公开(公告)号:DE4422335A1
公开(公告)日:1996-01-04
申请号:DE4422335
申请日:1994-06-27
Applicant: BASF AG
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公开(公告)号:DE19521033A1
公开(公告)日:1996-01-04
申请号:DE19521033
申请日:1995-06-09
Applicant: BASF AG
Inventor: DELAVIER PAUL DR , REICHELT HELMUT DR , MERGER ROLAND DR
IPC: C07B37/04 , C07C17/26 , C07C205/06 , C07C253/30 , C07C255/51 , C07C15/52 , C07C2/76 , C07C2/86 , C07C17/263 , C07C25/24 , C07C201/12 , C07C255/50
Abstract: Bis-styrylbenzenes of formula (I) are prepd. by reacting divinylbenzenes of formula (II) with benzene derivs. of formula A-X (III) in presence of a base and of a Pd (cpd.) catalyst forming labile Pd(0) cpds. under the reaction conditions, and opt. in presence of an inert organic diluent. A = mono- to penta-substd. phenyl (where the substits. are CN, COOH, 1-6C alkoxycarbonyl, carbamoyl, mono- or di-(1-6C) alkylcarbamoyl, 1-4C alkanoyl, 1-6C alkyl-sulphonyl, phenylsulphonyl, amino, mono- or di-(1-6C) alkylamino, NO2, halo, 1-6C alkoxy, opt. substd. phenoxy, 1-4C alkanoyloxy, hydroxysulphonyl, 1-6C alkoxysulphonyl, 1-6C alkyl or phenyl); X = COCl or COBr.
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公开(公告)号:DE4407018A1
公开(公告)日:1994-09-08
申请号:DE4407018
申请日:1994-03-03
Applicant: BASF AG
Inventor: GRUND CLEMENS DR , BACH VOLKER DR , LANGE ARNO DR , REICHELT HELMUT DR
IPC: C09B29/085 , C07C255/65 , C07C311/08 , C09B29/01 , C09B29/08 , D06P1/18 , C07C245/08
Abstract: Azo dyes of the formula in which one of the two radicals X and X is cyano and the other is hydrogen, R and R are optionally substituted C3-C4-alkenyl, benzyl or substituted C2-C4-alkyl, and R is optionally substituted C1-C4-alkanoyl or C1-C4-alkylsulphonyl, and their use for the dyeing or printing of textile materials.
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公开(公告)号:DE4306391A1
公开(公告)日:1994-09-08
申请号:DE4306391
申请日:1993-03-02
Applicant: BASF AG
Inventor: BACH VOLKER DR , LANGE ARNO DR , REICHELT HELMUT DR , ROTHMAIER HERBERT
Abstract: Dye mixtures comprising one or more red azo dyes of the formula where D is the radical of a diazo component of the aminothiophene series, one of X and X is a radical of the formula and the other is a radical of the formula NH-R , where L is substituted or unsubstituted C2-C8-alkylene, R is hydrogen or substituted or unsubstituted C1-C4-alkyl, R is hydrogen, C1-C4-alkyl, benzyl, phenyl or C1-C8-alkanoyl, and R is hydrogen, substituted or unsubstituted C1-C4-alkyl or a radical of the formula L-OR , and X is hydrogen or C1-C4-alkyl, 1,8-bis(phenylthio)anthraquinone and/or one or more dyes of the formula where Y , Y , Y , Y and Y are each hydrogen, C1-C4-alkyl, C 1-C4-alkoxy or phenoxy, 1,5-dihydroxy-4-phenylamino-8-nitroanthraquinone and/or 4,5-dihydroxy-1-phenylamino-8-nitroanthraquinone, and preparations thereof are useful for dyeing or printing textile materials.
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公开(公告)号:DE4404589A1
公开(公告)日:1994-08-25
申请号:DE4404589
申请日:1994-02-12
Applicant: BASF AG
Inventor: GRUND CLEMENS DR , GLAS GUENTHER DR , GUENTHERT PAUL DR , REICHELT HELMUT DR , BECKER RAINER DR , LANGE ARNO DR , FRIEDRICH KLAUS DR
IPC: B01J23/22 , C07B61/00 , C07C253/28 , C07C255/51 , C07C255/53 , C07C255/54 , C07C255/58 , C07D209/48 , C07D295/14 , C07D295/155
Abstract: Process for the preparation of dicyanobenzenes of the formula in which X is hydroxyl, C1-C4-alkoxy, nitro or optionally substituted amino, in which a xylene of the formula in which X has the abovementioned meaning is oxidised with oxygen in the presence of ammonia and of a catalyst at a temperature of 400 to 500 DEG C.
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公开(公告)号:DE59003652D1
公开(公告)日:1994-01-13
申请号:DE59003652
申请日:1990-04-05
Applicant: BASF AG
Inventor: HAHN ERWIN DR , HANSEN GUENTER DR , ETZBACH KARL-HEINZ DR , REICHELT HELMUT DR , SCHEFCZIK ERNST DR , DEGEN HELMUT , KRALLMANN REINHOLD , WAGENBLAST GERHARD DR
IPC: C09B29/033 , C09B67/22
Abstract: Navy blue and black dyestuff mixtures, containing one or more thiopheneazo dyestuffs whose diazo component is derived from the 2-aminothiophene series and whose coupling component is derived from the aniline series, and one or more dyestuffs F whose absorption maximum is at a wavelength of 390 to 520 nm, where the amount of the thiopheneazo dyestuffs is 60 to 99% by weight, relative to the total weight of the thiopheneazo dyestuffs and the dyestuffs F in the mixture.
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公开(公告)号:DE4132074A1
公开(公告)日:1993-04-01
申请号:DE4132074
申请日:1991-09-26
Applicant: BASF AG
Inventor: HAHN ERWIN DR , GRUND CLEMENS DR , GEISBERGER ANDREAS DR , REICHELT HELMUT DR , GULDNER ANDREAS DR , WIESENFELDT MATTHIAS DR , ETZBACH KARL-HEINZ DR , SENS RUEDIGER DR , HAGEN HELMUT DR
IPC: C09B29/00 , C09B29/039 , C09B29/042 , C09B29/045 , C09B29/44 , C09B29/033
Abstract: Azo dyes of the formula in which R and R in each case denote optionally substituted C1-C10-alkyl or optionally substituted C3-C4-alkenyl or R additionally denotes hydrogen, R denotes hydrogen or C1-C6-alkyl, R and R in each case denote hydrogen, C1-C6-alkyl, halogen, C1-C6-alkoxy, amino or C1-C4-mono- or dialkylamino and D denotes a radical from the thiophene, thiazole, isothiazole, benzothiophene, thienothiophene or thienothiazole series and their use for dyeing or printing textile fibres or fabrics or for thermal transfer.
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公开(公告)号:DE4131143A1
公开(公告)日:1993-03-25
申请号:DE4131143
申请日:1991-09-19
Applicant: BASF AG
Inventor: AUMUELLER ALEXANDER DR , EBERLE WOLFGANG DR , HEINZ GERHARD DR , HUPFELD BERND DR , HUSEMANN CHRISTIANE DR , KOCH JUERGEN DR , REICHELT HELMUT DR
Abstract: Prepn. of polyarylethers (I) or (II) by condensation of at least one corresp. bisphenol with at least one corresp. dichloro-aromatic in a polar aprotic solvent contg. an alkali metal carbonate and in the presence of a catalyst comprising alkali metal nitrites and cpds., where X, X', Q, Q', W, W' = -SO2, -O-, -CO-, a chemical bond or -CRR'-; R,R' = H, 1-6C alkyl or alkoxy, aryl or their fluorinated or chlorinated derivs.; p,q,r = 0,1; R1,R3 = H, 7-16C phenylalkyl, 1-12C alkoxy, F, Cl, Br, I or a nitro gp.; R2 = a nitro or nitroso gp. or (IV), (V) or (VI), where R4 = H, 1-4C alkyl, F, Cl, Br or I.
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公开(公告)号:DE4029732A1
公开(公告)日:1992-03-26
申请号:DE4029732
申请日:1990-09-20
Applicant: BASF AG
Inventor: WIESENFELDT MATTHIAS DR , GRUETTNER SABINE DR , ETZBACH KARL-HEINZ DR , REICHELT HELMUT DR
IPC: C07D277/42 , C07D277/54 , C07D277/56
Abstract: 2-Aminothiazoles of formula (I) and their tautomers are new: R1 = NH2 or N=C(T1)-NT2T3; T1 = H, 1-6C alkyl or Ph; T2 and T3 = 1-6C alkyl, 5-7C cycloalkyl or Ph, or NT2T3 is a satd. 5- to 7-membered ring opt. contg. other heteroatoms; R3 = S(O)nX, SH or Y; n = 0-2; X = 3-8C cycloalkyl or opt. substd. 1-20C alkyl, 3-6C alkenyl, 3-6C alkynyl or phenyl; Y = 1-20C mono- or dialkylamino (opt. substd. and/or interrupted by O), 3-8C cycloalkylamino, adamantylamino, 2-12C mono- or dialkenylamino, 3-12C alkynylamino, N-(1-5C alkyl)anilino, pyrrolidino, piperidino, morpholino, thiomorpholino, 1-piperazinyl, 4-(1-4C alkyl)-1-piperazinyl, hexamethylenimino, 1-imidazolyl, 1-pyrazolyl, opt. substd. anilino, pyridylamino, thienylamino, NHNH2, 1-4C mono- or dialkylhydrazino or phenylhydrazino; R4 = 1-6C alkanoyl, benzoyl, CN, COT4 or C(T6)T5; T4 = OH, 1-6C alkoxy, NH2 or Y; T5 = H, 1-6C alkyl or Ph; T6 = NOH, NQ or the residue of a cpd. contg. a reactive CH2 gp.; Q = opt. substd. 1-20C alkyl (opt. interrupted by O), an opt. substd. 3-6C alkenyl, 3-6C alkynyl, 3-12C cycloalkyl or phenyl gp., pyridyl, 3-6C alkoxycarbonylmethyl, NH2, dialkylamino or anilino; provided that: (a) R3 is not SCH(COMe)COOETt or SCH(COMe)2 when R1 = NH2 and R4 = COMe or COOEt; (b) R3 is not SMe when R1 = NH2 and R4 = CN; (c) R1 is not NH2 when R3 = piperidino or morpholino and R4 = CN.
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公开(公告)号:DE4003780A1
公开(公告)日:1991-08-14
申请号:DE4003780
申请日:1990-02-08
Applicant: BASF AG
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