Abstract:
Compositions including at least three metals (M1, M2, M3) are disclosed. The first metal (M1) is at least one metal selected from the iron group or the manganese group, and is preferably selected from iron, manganese, cobalt and nickel. The second metal (M2) is at least one metal selected from the rare earth group and is preferably selected from cerium, lanthanum, neodymium and praseodymiium. The third metal (M3) is selected from the group of alkaline or alkaline-earth metals, and is preferably selected from barium, strontium, calcium and lithium. The weight ratio (R) of metal (M3) to metal (M2) is greater than 0.15, and preferably greater than 1.5.
Abstract:
A process of improving the oxidation of carbonaceous products derived from the combustion of fuel and improving combustion of a fuel is described. The process comprises adding to the fuel before combustion thereof a composition comprising at least an organo-metallic complex of a Group I or Group II metal characterized in that the concentration of the complex in the fuel before combustion is 30 ppm or less.
Abstract:
A method improves the operation of a diesel engine through the use of a fuel additive, a diesel particulate trap and a NO.sub.x -reducing catalyst. The operation of the NO.sub.x -reducing catalyst is enhanced by the introduction of urea or like compound upstream of the catalyst at temperatures effective for non-catalytic NO.sub.x reduction and the generation of ammonia. The additive comprises fuel-soluble compositions of platinum group metal in effective amounts to lower the emissions of unburned hydrocarbons and carbon monoxide from the trap. The catalytic activity provided to the exhaust system by the fuel additive is selective and preferably reduces the oxidation of SO.sub.2 to SO.sub.3. The platinum group metal compositions are preferably added in amounts effective to provide concentrations of the metal in the fuel of less than 1 part per million (ppm). Lithium and/or sodium compositions can be used in amounts effective to reduce the trap regeneration temperature, e.g. concentrations to provide about 1 to 100 ppm lithium metal, and/or 1 to 30 ppm sodium metal.
Abstract:
Hydrocarbonaceous fuels and additive compositions therefor which comprise: a) one or more fuel-soluble manganese carbonyl compounds; and b) one or more fuel-soluble alkali or alkaline earth metal-containing neutral or basic detergent salts. These compositions preferably contain, in addition to components a) and b) above, one or more of the following: c) one or more fuel-soluble ashless dispersants; d) at least one fuel-soluble demulsifying agent; e) at least one aliphatic or cycloaliphatic amine; and f) at least one metal deactivator. The compositions possess improved combustion characteristics (e.g., formation of less soot, smoke, carbonaceous products and/or noxious emissions), and form on combustion carbonaceous products of reduced acidity. The deposition of sludge on critical engine or burner parts or surfaces is reduced and the fuels have improved stability and demulsibility characteristics. And the fuel compositions can result in decreased fuel consumption in diesel engines.
Abstract:
A fuel additive comprising a urethane compound. A gasoline composition comprising gasoline blended with a urethane compound to suppress sludge or deposits in fuel intake systems or combustion chambers, such as an automobile engine.
Abstract:
The present invention is directed to the use of hydantoin-containing polyether alcohols as additives in a gasoline composition. The invention is also directed to the use of these compounds for decreasing intake valve deposits, controlling octane requirement increases and reducing octane requirement. The invention is further directed to hydantoin-containing compounds.
Abstract:
A lubricant-fuel mixture containing an amine salt and/or amide of a thiobenzoic acid derivative is effective in reducing the smoke emitted during operation of a two-cycle internal combustion engine. A preferred thiobenzoic acid derivative is 4-hydroxy-3,5-ditert-dibutyldithiobenzoate.
Abstract:
A fuel composition for internal combustion engines, and more particularly, a fuel composition for internal combustion engines containing less than about 0.5 gram of lead per gallon of fuel is described. The fuel provides acceptable valve seat protection in engines designed to operate on leaded fuels. A further aspect of the invention is to reduce deposit formation within the cylinders.
Abstract:
A fuel composition for spark-ignition engines consisting essentially of gasoline and a barium compound in an amount of 100 ppm or more in terms of barium metal and relative to the gasoline, said barium compound being selected from the group consisting of a barium sulfonate, a barium naphthenate, a barium alkylsalicylate and a barium .alpha.-alkylalkane monocarboxylate. Spark-ignition engines utilizing this fuel composition operate with improved characteristics relative to adhesion of carbon to the spark plugs. The exhaust from the engine does not degrade the exhaust gas purifying catalyst even when the engine is equipped with an exhaust ignition control device.
Abstract:
This invention relates to basic magnesium salts of substituted aromatic hydroxy carboxylic acids or the derivatives thereof and to a process for preparing such salts. These salts can be used either along or in combination, as additives, in a variety of lubricating oils and fuels including gasoline, diesel fuels, etc.