11.
    发明专利
    未知

    公开(公告)号:DE102004033554A1

    公开(公告)日:2006-02-16

    申请号:DE102004033554

    申请日:2004-07-09

    Applicant: BASF AG

    Abstract: A process for the hydrogenation of an organic compound containing at least one carbonyl group comprises bringing the organic compound in the presence of hydrogen into contact with a shaped body which can be produced by a process in which (i) an oxidic material comprising copper oxide, aluminum oxide and aluminum oxide is made available (ii) pulverulent metallic copper, copper flakes, pulverulent cement, graphite or a mixture thereof is added to the oxidic material, and (iii) the mixture resulting from (ii) is shaped to form a shaped body.

    METHOD FOR THE PRODUCTION OF 1,6-HEXANEDIOL

    公开(公告)号:CA2508727A1

    公开(公告)日:2004-07-01

    申请号:CA2508727

    申请日:2003-12-03

    Applicant: BASF AG

    Abstract: The invention relates to a method for producing 1,6-hexanediol having a puri ty of > 99.5 wt. % by catalytic dimerisation of acrylic acid esters, catalyt ic hydrogenation of the thus obtained hexene diacidic diester in order to form 1.6-hexanediol. Said method consists in: a) dimerising C1- C8-acrylic acid esters in the presence of at least one rhodium compound in order to form mixtures predominantly of 2- and 3-hexene diacdic diesters, b) hydrating the obtained dimerisation discharge in the presence of chrome-free catalysts containing mainly copper as a hydrogenation component and c) purifying the thus obtained raw 1.6-hexanediol by fractionating distillation.

    PROCEDIMIENTO PARA LA PRODUCCION DE 1,6-HEXANODIOL.

    公开(公告)号:ES2270165T3

    公开(公告)日:2007-04-01

    申请号:ES03799469

    申请日:2003-12-03

    Applicant: BASF AG

    Abstract: Procedimiento para la producción de 1,6-hexanodiol con una pureza de >_99,5% en peso mediante dimerización catalítica de ésteres del ácido acrílico e hidrogenación catalítica de los diésteres del ácido hexenodioico así obtenidos para dar 1,6-hexanodiol, en el que a) se dimeriza el éster del ácido acrílico de C1 a C8 en presencia al menos de un compuesto de rodio para dar mezclas predominantemente de diésteres de los ácidos 2 y 3-hexenodioico, b) se hidrogena el producto de salida de la dimerización obtenido en presencia de catalizadores que contienen predominantemente cobre como componente de hidrogenación, libres de cromo y c) se purifica el 1,6-hexanodiol bruto así obtenido mediante la destilación fraccionada.

    15.
    发明专利
    未知

    公开(公告)号:DE102005031316A1

    公开(公告)日:2007-01-18

    申请号:DE102005031316

    申请日:2005-07-05

    Applicant: BASF AG

    Abstract: Process for recovering cyclododecatriene (CDT) from a solution containing CDT and high boilers such as deactivated catalyst and polymers, which includes feeding the solution into a preheater and heating it, subsequently depressurizing it through a downstream pressure maintenance device and feeding the resulting two-phase mixture into a helical tube evaporator and there reducing the CDT content of the liquid phase by partial evaporation and discharging a gaseous product stream having an increased concentration of CDT.

    18.
    发明专利
    未知

    公开(公告)号:BRPI0408384A

    公开(公告)日:2006-03-21

    申请号:BRPI0408384

    申请日:2004-03-20

    Applicant: BASF AG

    Abstract: A process for hydrogenating an organic compound which has at least one carbonyl group, in which the organic compound is hydrogenated in the presence of a shaped article which contains (i) an oxidic material comprising copper oxide, aluminum oxide and lanthanum oxide, and (ii) powdered metallic copper, copper flakes, powdered cement, graphite or a mixture thereof, is provided.

    19.
    发明专利
    未知

    公开(公告)号:DE102004007498A1

    公开(公告)日:2005-09-01

    申请号:DE102004007498

    申请日:2004-02-13

    Applicant: BASF AG

    Abstract: The present invention relates to a process for preparing optically active hydroxy-, alkoxy-, amino-, alkyl-, aryl- or chlorine-substituted alcohols or hydroxy carboxylic acids having from 3 to 25 carbon atoms or their acid derivatives or cyclization products by hydrogenating the correspondingly substituted optically active mono- or dicarboxylic acids or their acid derivatives in the presence of a catalyst whose active component comprises a noble metal selected from the group of the metals Pt, Pd, Rh, Ir, Ag, Au and at least one further element selected from the group of the elements: Sn, Ge, Mo, W, Ti, Zr, V, Mn, Fe, Co, Ni, Cu, Zn, Ga, In, Pb, Bi, Cr, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu.

    HYDROGENATION METHOD FOR PRODUCING OPTICALLY ACTIVE ALCOHOLSOR CARBOXYLIC ACIDS

    公开(公告)号:CA2553700A1

    公开(公告)日:2005-08-25

    申请号:CA2553700

    申请日:2005-02-08

    Applicant: BASF AG

    Abstract: The invention concerns a method for producing optically active hydroxy-, alkoxy-, amino-, alkyl-, aryl- or chlorine-substituted alcohols or hydroxycarboxylic acids having 3 to 25 carbon atoms or their acid derivative s or cyclization products by hydrogenating the correspondingly substituted optically active monocarboxylic acids or dicarboxylic acids or their acid derivatives in the presence of a catalyst whose active constituent contains a noble metal selected from the group of metals consisting of Pt, Pd, Rh, Ir, Ag, Au and at least one additional element selected from the group of elemen ts consisting of Sn, Ge, Mo, W, Ti, Zr, V, Mn, Fe, Co, Ni, Cu, Zn, Ga, In, Pb, Bi, Cr, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu.

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