公开(公告)号：DE10163335A1

公开(公告)日：2003-07-10

申请号：DE10163335

申请日：2001-12-21

Applicant: BASF AG

Inventor： KAIBEL GERD ,  MILLER CHRISTIAN ,  KLAS KATRIN ,  KINDLER ALOIS ,  AQUILA WERNER ,  DOBLER WALTER ,  BREUER KLAUS ,  POMMER ACHIM ,  DIRNSTEINER THOMAS

IPC: B01D3/26 ,  B01D3/14 ,  B01D3/00

Abstract: Distillation column has a dividing wall which divides it into inflow and extraction sections, and upper and lower column zones. The mixture for distillation comprises a vapor feed which enters between the upper and lower inflow sections, between which the side extraction point removes vapor. The inflow and the extraction zones are offset relative too the dividing wall. The vapor feed rate is equal in all zones of the column. The distillation column has a dividing wall (TW) which divides it into an inflow section (2,4), an extraction section (3,5), and common upper (1) and lower (6) column zones. The mixture for distillation is at least partially a vapor feed (F) which enters between the upper and lower inflow sections, and the side extraction point (B) removes vapor between the upper and lower extraction zones. The cross sectional surfaces of the inflow and the extraction zones are set by an offset in the dividing wall. The F-factor is equal in all the zones of the column, defined as the product of the gas flow speed in m/seconds multiplied with the square root of the gas density in kg/m3.

公开(公告)号：DE59805907D1

公开(公告)日：2002-11-14

申请号：DE59805907

申请日：1998-06-29

Applicant: BASF AG

Inventor： KNOLL KONRAD ,  KINDLER ALOIS ,  FISCHER WOLFGANG

IPC: C08L53/00 ,  C08C19/44 ,  C08F4/00 ,  C08F297/00 ,  C08F297/02 ,  C08F297/04 ,  C08G81/02

Abstract: New oximsulfonate compounds of formulae (I) or (II), wherein m is 0 or 1; x is 1 or 2; R1 is, for example phenyl, which is unsubstituted or substituted or R1 is a heteroaryl radical that is unsubstituted or substituted, or, if m is 0, R1 additionally is C2-C6alkoxycarbonyl, phenoxycarbonyl or CN; R'1 is for example C2-C12alkylene, phenylene; R2 has for example one of the meanings of R1; n is 1 or 2; R3 is for example C1-C18alkyl, R'3 when x is 1, has one of the meanings given for R3, or R'3 in formula (IV) and when x is 2 in formula (I), is for example C2-C12 alkylene, phenylene; R4 and R5 are independently of each other for example hydrogen, halogen, C1-C6alkyl; R6 is for example hydrogen, phenyl; R7 and R8 are independently of each other for example hydrogen or C1-C12alkyl; R9 is for example C1-C12alkyl; A is S, O, NR6, or a group of formula (A1), (A2), (A3) or (A4); R10 and R11 independently of each other have one of the meanings given for R4; R12, R13, R14 and R15 independently of one another are for example hydrogen, C1-C4alkyl; Z is CR11 or N; Z1 is -CH2-, S, O or NR6, are useful as latent sulfonic acids, especially in photoresist applications.

公开(公告)号：DE19924020A1

公开(公告)日：2000-11-30

申请号：DE19924020

申请日：1999-05-26

Applicant: BASF AG

Inventor： KINDLER ALOIS ,  PREISS THOMAS ,  HENKELMANN JOCHEM

IPC: B01J31/02 ,  C07B61/00 ,  C07C29/42 ,  C07C33/044 ,  C07C33/046 ,  C07C29/44

Abstract: Alkyne diol preparation from a carbonyl compound and acetylene uses an alkali metal salt prepared in situ as an alcoholate a catalyst. Preparation of alkyne diol of formula (I)comprises reacting a carbonyl compound of formula (II) with acetylene in the prese of an alkali metal salt as catalyst and a polar aprotic solvent. R R C(OH)-C IDENTICAL C-C(OH)R R (I) R -C(=O)-R (II) R and R = H or 1-20C hydrocarbon optionally substituted by 1-6C alkyl and/or halogen and/or interrupted by halogen and/or containing a CC double or triple bond.

公开(公告)号：CA2340697A1

公开(公告)日：2000-02-24

申请号：CA2340697

申请日：1999-08-13

Applicant: BASF AG

Inventor： TRAGUT CHRISTIAN ,  HENKELMANN JOCHEM ,  KINDLER ALOIS ,  BRUNNER MELANIE

IPC: C07B61/00 ,  C07C29/42 ,  C07C33/044

Abstract: The invention relates to a method for producing alkyne diols by reacting ketones with acetylenic hydrocarbons in an organic solvent in the presence o f a base which contains potassium alcoholates of primary and/or secondary alcohols. The alkyne diols are produced while forming adducts which precipitate out of the reaction mixture and which are comprised of alkyne monoalcohols and/or alkyne diols and a base. The stoichiometries of the reaction partners are selected such that gelatinous adducts are formed which comprise a spherical surface, whereby the reaction mixture remains agitable during the entire reaction.

公开(公告)号：AT384706T

公开(公告)日：2008-02-15

申请号：AT02016707

申请日：2002-07-26

Applicant: BASF AG

Inventor： RUST HARALD ,  BURKART KIRSTEN ,  FAUST TILLMANN ,  HENKELMANN JOCHEM ,  KINDLER ALOIS ,  KNOLL CHRISTIAN ,  MOHRY ANDRE

IPC: C07D263/42

Abstract: Continuous production of 5-alkoxy oxazoles (I) comprises heating an alkyl alpha -isocyanoalkanoate ester (II) at a temperature above 80 degrees C in the presence of an auxiliary agent and withdrawing the product from the reactor. Continuous production of 5-alkoxy oxazoles of formula (I) comprises heating an alkyl alpha -isocyanoalkanoate ester of formula (II) at a temperature above 80 degrees C in the presence of an auxiliary agent and withdrawing the product from the reactor. R1 = optionally substituted 1-6C alkyl; R2 = H or optionally substituted 1-6C alkyl. An Independent claim is also included for a process for producing pyridoxine derivatives of formula (IX), comprising: (1) converting an amino acid of formula (III) to an ester of formula (IV); (2) converting (IV) to a formamido ester of formula (IV); (3) converting (IV) to (II); (4) converting (II) to (I) as above; (5) reacting (I) with a protected diol of formula (VI) to form a Diels-Alder adduct of formula (VII); and (6) converting (VII) to (IX) by acid treatment and deprotection. R3, R4 = protecting groups or together form a protecting group.

公开(公告)号：DE59813874D1

公开(公告)日：2007-02-22

申请号：DE59813874

申请日：1998-06-10

Applicant: BASF AG

Inventor： STAMM ARMIN ,  JULIUS MANFRED ,  KINDLER ALOIS ,  HENNINGSEN MICHAEL ,  BOTZEM JOERG

IPC: C07D233/60 ,  C07D233/56 ,  C07D233/80

Abstract: Carbonyldiimidazoles of the formulae Ia, Ib, Ic or mixtures thereofwhere R1 is C1-4-alkyl and R2 is hydrogen or methyl, and tert-butyl esters derived therefrom are described.

公开(公告)号：AU2003285305A1

公开(公告)日：2004-06-07

申请号：AU2003285305

申请日：2003-10-28

Applicant: BASF AG

Inventor： DOBLER WALTER ,  BAHR NICOLAUS ,  BREUER KLAUS ,  KINDLER ALOIS

IPC: C07C45/54 ,  C07C45/74 ,  C07C49/203 ,  C07C403/16

Abstract: The invention relates to a continuous process for producing pseudoionones of general formulas (I) and (I') as well as isomers thereof, whereby: R 1 represents CH 3 or (a); R 2 and R 3 represent hydrogen, CH 3 or C 2 H 5 , and; R 4 and R 5 represent hydrogen or CH 3 . These pseudoionones are produced by reacting an aldehyde of formula (II) with an excess of a ketone of general formula (III), whereby R 1 , R 2 and R 3 have the aforementioned meanings, in the presence of water and alkali hydroxide at an increased temperature and in a homogeneous solution. The inventive process is characterized in that: a) the intermixing of the homogeneous solution consisting of aldehyde, ketone and aqueous alkali lye occurs at a temperature ranging from 10 to 120° C.; b) the undissolved water and alkali hydroxide contained in the reaction mixture are subsequently separated out; c) while avoiding back mixing, the homogeneous reaction mixture is then guided through a reactor, which permits a residence time ranging from 2 to 300 minutes, at a temperature that is 10 to 120° C. higher than the boiling point of the lowest-boiling component and under a vapor pressure p ranging from 10 6 to 10 7 Pa; d) the reaction mixture is cooled by expansion; e) ketone is removed from the reaction mixture using vapor flowing in the opposite direction and; f) the raw product is dried and rid from excessive aldehyde and secondary components via a rectification column.

公开(公告)号：CA2505094A1

公开(公告)日：2004-05-21

申请号：CA2505094

申请日：2003-10-28

Applicant: BASF AG

Inventor： BREUER KLAUS ,  KINDLER ALOIS ,  BAHR NICOLAUS ,  DOBLER WALTER

IPC: C07C45/54 ,  C07C45/74 ,  C07C49/203 ,  C07C403/16

Abstract: The invention relates to a continuous process for producing pseudoionones of general formulas (I) and (I.prime.) as well as isomers thereof, whereby: R1 represents CH3 or (a); R2 and R3 represent hydrogen, CH3 or C2H5, and; R4 an d R5 represent hydrogen or CH3. These pseudoionones are produced by reacting a n aldehyde of formula (II) with an excess of a ketone of general formula (III) , whereby R1, R2 and R3 have the aforementioned meanings, in the presence of water and alkali hydroxide at an increased temperature and in a homogeneous solution. The inventive process is characterized in that: a) the intermixing of the homogeneous solution consisting of aldehyde, ketone and aqueous alkal i lye occurs at a temperature ranging from 10 to 120 ~C; b) the undissolved water and alkali hydroxide contained in the reaction mixture are subsequentl y separated out; c) while avoiding back mixing, the homogeneous reaction mixtu re is then guided through a reactor, which permits a residence time ranging fro m 2 to 300 minutes, at a temperature that is 10 to 120 ~C higher than the boiling point of the lowest-boiling component and under a vapor pressure p ranging from 106 to 107 Pa; d) the reaction mixture is cooled by expansion; e) ketone is removed from the reaction mixture using vapor flowing in the opposite direction and; f) the raw product is dried and rid from excessive aldehyde and secondary components via a rectification column.

公开(公告)号：DE10209458A1

公开(公告)日：2003-09-18

申请号：DE10209458

申请日：2002-03-05

Applicant: BASF AG

Inventor： KINDLER ALOIS ,  HENKELMANN JOCHEM ,  BECKER MICHAEL ,  RUST HARALD ,  KNOLL CHRISTIAN ,  BURKART KIRSTEN

IPC: C07D263/42 ,  C07B37/12 ,  C07D213/67

公开(公告)号：DK1105362T3

公开(公告)日：2003-02-24

申请号：DK99941607

申请日：1999-08-13

Applicant: BASF AG

Inventor： KINDLER ALOIS ,  BRUNNER MELANIE ,  TRAGUT CHRISTIAN ,  HENKELMANN JOCHEM

IPC: C07B61/00 ,  C07C29/42 ,  C07C33/044

Abstract: The invention relates to a method for producing alkyne diols by reacting ketones with acetylenic hydrocarbons in an organic solvent in the presence of a base which contains potassium alcoholates of primary and/or secondary alcohols. The alkyne diols are produced while forming adducts which precipitate out of the reaction mixture and which are comprised of alkyne monoalcohols and/or alkyne diols and a base. The stoichiometries of the reaction partners are selected such that gelatinous adducts are formed which comprise a spherical surface, whereby the reaction mixture remains agitable during the entire reaction.