24.
    发明专利
    未知

    公开(公告)号:AT358113T

    公开(公告)日:2007-04-15

    申请号:AT00956304

    申请日:2000-07-26

    Applicant: BASF AG

    Abstract: A description is given of a process for preparing methyl formate by reacting excess methanol with carbon monoxide under superatmospheric pressure and at elevated temperature in the presence of alkali metal methoxide or alkaline earth metal methoxide as catalyst in a pressure-rated reactor, in which the use of at least two reactor elements, preferably operated in countercurrent, at about 100° C. and a pressure of about 100 bar in combination with a solids-free desalting of the reaction product makes possible very economical, largely trouble-free production of methyl formate in any desired quality and with a very good production capacity. Furthermore, the process for solids-free desalting and apparatuses for carrying out this process are described.

    27.
    发明专利
    未知

    公开(公告)号:ES2178755T3

    公开(公告)日:2003-01-01

    申请号:ES97906172

    申请日:1997-03-05

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP97/01113 Sec. 371 Date Sep. 4, 1998 Sec. 102(e) Date Sep. 4, 1998 PCT Filed Mar. 5, 1997 PCT Pub. No. WO97/32866 PCT Pub. Date Sep. 12, 1997A noble metal-free catalyst composition is obtainable by a) preparing an aqueous mixture comprising i) a salt of at least one base metal selected from among the elements having atomic numbers 21-32, 39-42, 48-51, 57-75 and 81-83; ii) phosphate ions; and iii) at least one nitrogen source; and b) evaporating the aqueous mixture obtained and drying the catalyst composition thus formed. The catalyst composition prepared can be used for producing hydrogen peroxide and for the epoxidation of olefins.

    28.
    发明专利
    未知

    公开(公告)号:ES2172201T3

    公开(公告)日:2002-09-16

    申请号:ES98946393

    申请日:1998-08-20

    Applicant: BASF AG

    Abstract: Ruthenium complexes of the formula I or IVwhereX, Y are anionic ligands,R is hydrogen or a substituted or unsubstituted C1-C20-alkyl radical or C6-C20-aryl radical andL1 and L2 are, independently of one another, uncharged electron donor ligands, are prepared by(a) reaction of RuX3 with L1 and L2 in an inert solvent in the presence of a reducing agent and hydrogen and(b) reaction with compounds of the formula IIwhere R is as defined above, in the presence or absence of water, and, if desired after isolation of the intermediate, with HY, [HL1]Y or [HL2]Y.

    30.
    发明专利
    未知

    公开(公告)号:DK1005476T3

    公开(公告)日:2002-03-25

    申请号:DK98946393

    申请日:1998-08-20

    Applicant: BASF AG

    Abstract: Ruthenium complexes of the formula I or IVwhereX, Y are anionic ligands,R is hydrogen or a substituted or unsubstituted C1-C20-alkyl radical or C6-C20-aryl radical andL1 and L2 are, independently of one another, uncharged electron donor ligands, are prepared by(a) reaction of RuX3 with L1 and L2 in an inert solvent in the presence of a reducing agent and hydrogen and(b) reaction with compounds of the formula IIwhere R is as defined above, in the presence or absence of water, and, if desired after isolation of the intermediate, with HY, [HL1]Y or [HL2]Y.

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