公开(公告)号：DE59902838D1

公开(公告)日：2002-10-31

申请号：DE59902838

申请日：1999-03-01

Applicant: BASF AG

Inventor： DR BOETTCHER ARND ,  HENKELMANN JOCHEM ,  BROECKER JOSEF ,  KAIBEL GERD ,  RUETTER HEINZ

IPC: B01J8/00 ,  B01J8/06 ,  B01J8/18 ,  B01J8/20 ,  B01J8/22 ,  B01J8/34 ,  B01J19/24 ,  C01B15/023 ,  C07C37/07

Abstract: In a process for the suspension hydrogenation of an anthraquinone compound or a mixture of two or more thereof in a reactor in which there are present the working solution in which at least one catalyst is suspended and, in addition, a hydrogen-containing gas phase, the working solution and the gas phase are, in the reactor, passed at least partly through a fitting having openings or channels whose hydraulic diameter is from 0.5 to 20 mm, preferably from 1 to 10 mm, particularly preferably from 1 to 3 mm.

公开(公告)号：ES2172354T3

公开(公告)日：2002-09-16

申请号：ES99955265

申请日：1999-05-21

Applicant: BASF AG

Inventor： BRUNNER MELANIE ,  RAHN RALF-THOMAS ,  RHEUDE UDO ,  HENKELMANN JOCHEM

IPC: C07D307/33 ,  C07D307/32 ,  C07D315/00

Abstract: Process for producing butyrolactones of the general formula Iwhere R1 and R2 are each hydrogen, alkyl, hydroxyalkyl, substituted or unsubstituted aryl or substituted or unsubstituted trialkylsilyl, by reacting alkynes of the general formula IIwhere R1 and R2 are each as defined above, with carbon monoxide and water in the presence of a rhodium catalyst under pressures from 20 to 300 bar and hydrogenating the unhydrogenated 2(5H)-furanone intermediates comprisesa) reacting the carbonylation reaction mixture with hydrogen at from 150 to 250° C. and from 100 to 300 bar,b) removing the precipitated catalyst and returning it into the carbonylation reaction, andc) subjecting the catalyst-free reaction mixture to a distillation to recover the butyrolactone.

公开(公告)号：CZ20021980A3

公开(公告)日：2002-09-11

申请号：CZ20021980

申请日：2000-11-27

Applicant: BASF AG

Inventor： STAMM ARMIN ,  GOTZ ROLAND ,  GOTZ NORBERT ,  HENKELMANN JOCHEM ,  KNEUPER HEINZ-JOSEF ,  WOLF BERND

IPC: C07C51/58 ,  C07B61/00 ,  C07C51/09 ,  C07C57/76

Abstract: The invention relates to a method for producing o-choromethyl benzenecarbonyl chlorides of formula (I), wherein R -R can be the same or different and stand for hydrogen, C1-C4-alkyl, halogen or trifluoromnethyl, by converting benzocondensed lactones of formula (II), wherein R -R have the aforementioned meaning, with gaseous or liquid phosgene and the dimers or trimers thereof. The inventive method is characterized in that the conversion is carried out in the presence of catalytical amounts of a Lewis acid and catalytical amounts of a phosgenation catalyst

公开(公告)号：PL348751A1

公开(公告)日：2002-06-03

申请号：PL34875199

申请日：1999-11-06

Applicant: BASF AG

Inventor： MAYWALD VOLKER ,  STEINMETZ ADRIAN ,  RACK MICHAEL ,  GOETZ NORBERT ,  GOETZ ROLAND ,  HENKELMANN JOCHEM ,  BECKER HEIKE ,  AISCAR BAYETO JUAN JOSE

IPC: C07D231/20

Abstract: The invention relates to a process for preparing 1-substituted 5- and/or 3-hydroxypyrazoles of the formulae I and IIin which R1 is C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C6-cycloalkyl or C1-C4-alkoxy, where these groups may be substituted by halogen, C1-C4-alkoxy, phenoxy, C1-C6-alkoxycarbonyl, C1-C6-alkylthiocarbonyl or by a cyclic ring system having 3-14 ring atoms, which comprises reactingan alkyl 3-alkoxyacrylate of the formula IIIin which R2, R3 independently of one another are C1-C6-alkyl or C3-C6-cycloalkyl with a hydrazine of the formula IVin which R1 is as defined abovea) at a pH of 6-11 to give 5-hydroxypyrazoles of the formula I orb) at a pH of 11-14 to give 3-hydroxypyrazoles of the formula II.

公开(公告)号：DE59803544D1

公开(公告)日：2002-05-02

申请号：DE59803544

申请日：1998-08-28

Applicant: BASF AG

Inventor： WEYER HANS-JUERGEN ,  STAMM ARMIN ,  WEBER THEODOR ,  HENKELMANN JOCHEM

IPC: B01J31/02 ,  C07B61/00 ,  C07C329/02

Abstract: PCT No. PCT/EP98/05525 Sec. 371 Date Feb. 17, 2000 Sec. 102(e) Date Feb. 17, 2000 PCT Filed Aug. 28, 1998 PCT Pub. No. WO99/11611 PCT Pub. Date Mar. 11, 1999A catalyst used for preparing thiochloroformates by reacting thiols with phosgene is a cyclic urea or cyclic thiourea which may be in the form of a salt obtainable by reaction with a hydrohalic acid or phosgene.

公开(公告)号：BG105538A

公开(公告)日：2002-04-30

申请号：BG10553801

申请日：2001-05-22

Applicant: BASF AG

Inventor： MAYWALD VOLKER ,  STEINMETZ ADRIAN ,  RACK MICHAEL ,  GOETZ NORBERT ,  GOETZ ROLAND ,  HENKELMANN JOCHEM ,  BECKER HEIKE ,  AISCAR BAYETO JUAN J

IPC: C07D231/20

Abstract: The invention relates to a method for producing 1-substituted 5- and/or 3-hydroxypyrazoles of formulae wherein R1 represents C1-C6-alkyl,C2-C6-alkenyl, C2-C6-alkinyl, C3-C6-cycloalkyl or C1-C4-alkoxy, whereby these groups can be substituted by halogen, C1-C4-alkoxy, phenoxy, C1-C6-alkoxycarbonyl, or a cyclic ring system with 3-14 ring atoms, by reacting a 3-alkoxyacrylic acid alkyl ester for formula wherein R2, R3 independently means C1-C6-alkyl or C3-C6 cycloalkyl, with a hydrazine or formula wherein R1 has the above cited meaning, a) at a pH value of 6-11 to form 5-hydroxypyrazoles of formula or b) at a pH value of 11-14 to form 3-hydroxypyrazoles of formula (II). 13 claims

公开(公告)号：DE10050709A1

公开(公告)日：2002-04-25

申请号：DE10050709

申请日：2000-10-13

Applicant: BASF AG

Inventor： BOETTCHER ARND ,  HENKELMANN JOCHEM ,  HAAKE MATHIAS ,  KAIBEL GERD

IPC: B01J23/46 ,  B01J23/40 ,  B01J23/56 ,  B01J35/04 ,  B01J37/02 ,  C07B35/02 ,  C07B61/00 ,  C07C5/10 ,  C07C13/18 ,  C07C209/72 ,  C07C211/35 ,  B01J32/00

Abstract: A structured catalyst support (I) contains a promoter comprising a Group I, II or IV metal or Group I-IV or VI metal and sulfur, selenium and carbon. Independent claims are included for; (i) a catalyst comprising a group VIII metal applied to the support (I); and (ii) a process for the hydrogenation of a mono- or multi-nuclear aromatic compounds, optionally substituted by at least one alkyl group, by contacting the aromatic compound with a hydrogen containing gas in the presence of a catalyst having at least one group (VIII) metal as the active metal applied to a structured or monolithic support.

公开(公告)号：AT215070T

公开(公告)日：2002-04-15

申请号：AT98948890

申请日：1998-08-28

Applicant: BASF AG

Inventor： WEYER HANS-JUERGEN ,  STAMM ARMIN ,  WEBER THEODOR ,  HENKELMANN JOCHEM

IPC: B01J31/02 ,  C07B61/00 ,  C07C329/02

Abstract: PCT No. PCT/EP98/05525 Sec. 371 Date Feb. 17, 2000 Sec. 102(e) Date Feb. 17, 2000 PCT Filed Aug. 28, 1998 PCT Pub. No. WO99/11611 PCT Pub. Date Mar. 11, 1999A catalyst used for preparing thiochloroformates by reacting thiols with phosgene is a cyclic urea or cyclic thiourea which may be in the form of a salt obtainable by reaction with a hydrohalic acid or phosgene.

公开(公告)号：DE59802965D1

公开(公告)日：2002-03-14

申请号：DE59802965

申请日：1998-06-05

Applicant: BASF AG

Inventor： GROSCH HEINRICH ,  MUELLER ULRICH ,  WALCH ANDREAS ,  RIEBER NORBERT ,  FISCHER MARTIN ,  QUAISER STEFAN ,  HARDER WOLFGANG ,  ELLER KARSTEN ,  BASSLER PETER ,  WENZEL ANNE ,  KAIBEL GERD ,  STAMMER ACHIM ,  HENKELMANN JOCHEM ,  BOETTCHER ARND ,  TELES HENRIQUE ,  SCHULZ MICHAEL ,  TREIBER GERT

IPC: B01J29/90 ,  B01J38/14 ,  C07B41/00 ,  C07B61/00 ,  C07D301/12 ,  C07D301/19

Abstract: A process for oxidizing an organic compound having at least one C-C double bond or a mixture of two or more thereof comprises the following steps:(I) preparing a hydroperoxide,(II) reacting an organic compound having at least one C-C double bond or a mixture of two or more thereof with the hydroperoxide prepared in step (I) in the presence of a zeolite catalyst,(III) regenerating the at least partially deactivated zeolite catalyst used in step (II), and(IV) conducting the reaction of step (II) using a zeolite catalyst containing the catalyst regenerated in step (III).

公开(公告)号：HU0104207A2

公开(公告)日：2002-02-28

申请号：HU0104207

申请日：1999-10-29

Applicant: BASF AG

Inventor： HENKELMANN JOCHEM ,  STAMM ARMIN

IPC: C07C51/60 ,  C07C53/42 ,  C07C53/50

Abstract: The invention relates to a process for the preparation of acid chlorides by reaction of carboxylic acids, carboxylic anhydrides, cyclic carboxylic esters or sulfonic acids with phosgene in the presence of a catalytic amount of a compound from the group consisting of N,N,N',N'-tetrasubstituted amidinium halides (I), N,N,N'-trisubstituted amidinium hydrohalides (II) and N,N,N'-trisubstituted amidines (III).