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公开(公告)号:DE19734445A1
公开(公告)日:1999-02-11
申请号:DE19734445
申请日:1997-08-08
Applicant: BASF AG
Inventor: KELLER HARALD DR , SCHEHLMANN VOLKER DR , WESTENFELDER HORST , PREISS THOMAS DR
IPC: A61K8/00 , A61K8/90 , A61Q1/00 , A61Q1/04 , A61Q5/00 , A61Q17/04 , C08F216/14 , C08F216/16 , C08F216/18 , C08F218/00 , C08F218/10 , C08F220/36 , C09K3/00 , G02B1/04 , C08F216/12 , C08F220/10 , C08F218/04 , A61K7/42
Abstract: Polymeric UV absorbers based on units of formula (I) are new, where a+b+c+d = 100; a, c = 5-95; b, d = 0-70; R , R = H or 1-8C alkyl; R = 3-hydroxy-4-benzoylphenoxy, a benzoyloxy group substituted in the 2-position by N(X )(X ), a group of formula (i)-(iv), 2-hydroxybenzoyloxy, 4-(2-oxo-3-bornylidenemethyl)phenoxy, 3-hydroxy-4-(benzylÄbÜ1,2,3-triazol-2-yl)phenoxy or 4-hydroxy-3-(benzylÄbÜ1,2,3-triazol-2-yl)benzoyloxy; X -X = H or 1-8C alkyl; R = (CO)n-R ; R = 1-28C alkyl; n = 0 or 1; R = 1-22C alkyl; R = H or CH3; and R (sic) = H or CH3.
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公开(公告)号:AU5210998A
公开(公告)日:1998-07-23
申请号:AU5210998
申请日:1998-01-16
Applicant: BASF AG
Inventor: DROGEMULLER MICHAEL , BOMM VOLKER , SCHEHLMANN VOLKER , WESTENFELDER HORST
IPC: C07D215/42 , A61K8/00 , A61Q17/04 , C07C225/14 , C07C229/54 , C07C237/30 , C07C309/46 , C07C311/39 , C09K3/00 , C07C309/29 , C07C311/38 , A61K7/42 , A61K31/165 , A61K31/18 , A61K31/135 , A61K31/185 , A61K31/47
Abstract: Arylaminomethylene-camphor derivatives of formula (I) are new: R1 = H or Me; R2 = H, 1-6C alkyl, 3-8C cycloalkyl, 2-6C alkenyl; 3-8C cycloalkenyl or aryl (optionally substituted); R3 = H, 1-6C alkyl, 3-8C cycloalkyl, aryl (optionally substituted), 1-6C alkoxy or 1-8C acyl; and Ar = aryl or heteroaryl (both optionally substituted); NB the double bond is Z or E configuration.
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公开(公告)号:DE19634229A1
公开(公告)日:1998-02-26
申请号:DE19634229
申请日:1996-08-23
Applicant: BASF AG
Inventor: HABECK THORSTEN , AUMUELLER ALEXANDER , SCHEHLMANN VOLKER , WESTENFELDER HORST , WUENSCH THOMAS
IPC: A61K8/00 , A61K8/30 , A61K8/40 , A61K8/49 , A61K8/92 , A61Q1/00 , A61Q1/04 , A61Q17/04 , C07C255/40 , C07D307/52 , C07D317/54 , C07D333/24 , A61K7/42
Abstract: The use of compounds of formula (I) as UV-A filters in cosmetic products (optionally in combination with standard UV absorbers) to protect the human skin against sunlight is claimed. R1-R3 = H or (cyclo)aliphatic group containing up to 18 C, or two of these groups can combine to form a 5 or 6-membered ring ; R4 = optionally substituted (hetero)aryl containing 5-12 ring atoms ; and R5 = R4 or H. Also claimed are (i) cosmetic products containing (I) for protecting the epidermis layer against UV radiation with a wavelength of 280-400 nm and (ii) compounds of formula (II) : R7-R9 = lower alkyl ; R6 = 2-thienyl (optionally substituted with lower alkyl), 4-(3,5-di-t-butyl)-1-hydroxyphenyl or 4-(3,5-di-t-butyl)-1-alkoxyphenyl.
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公开(公告)号:CA2211919A1
公开(公告)日:1998-02-26
申请号:CA2211919
申请日:1997-08-21
Applicant: BASF AG
Inventor: KELLER HARALD , SPERLING-VIETMEIER KARIN , WESTENFELDER HORST
Abstract: Cosmetic compositions contain a polymer with the repeating structural unit (I) (see fig.I) where the radicals have the meanings stated in the description.
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公开(公告)号:CA2248165A1
公开(公告)日:1997-09-18
申请号:CA2248165
申请日:1997-03-06
Applicant: BASF AG
Inventor: WESTENFELDER HORST , SCHEHLMANN VOLKER , KANDZIA CHRISTOF
IPC: A61K8/00 , A61K8/35 , A61K31/00 , A61K31/125 , A61P17/00 , A61P17/16 , A61Q17/04 , C07C45/51 , C07C45/74 , C07C49/683 , C07C49/697 , C07C49/753 , C07C225/22 , C09K15/06 , A61K7/00 , A61K31/135 , A61K7/42
Abstract: The invention relates to cinnamylidene camphor derivatives of the formula (1) in which the diene system is in the configuration Z,Z; Z,E; E,Z or E, E and R1 is H, CH3, R2 is C1-C6 alkyl, C1-C6 alkoxy, halogen, NR3H, NR32, R3 is C1-C4 alkyl, R4 is H, C1-C6 alkyl, and n is 1, 2, and their use as UV-A protecting agents, especially in cosmetical and pharmaceutical formulations.
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公开(公告)号:AU7491996A
公开(公告)日:1997-05-29
申请号:AU7491996
申请日:1996-10-25
Applicant: BASF AG
Inventor: HOLDERBAUM MARTIN , AUMULLER ALEXANDER , SPERLING KARIN , WESTENFELDER HORST , WUNSCH THOMAS
Abstract: PCT No. PCT/EP96/04637 Sec. 371 Date Apr. 29, 1998 Sec. 102(e) Date Apr. 29, 1998 PCT Filed Oct. 25, 1996 PCT Pub. No. WO97/17054 PCT Pub. Date May 15, 1997A sunscreen-containing cosmetic formulation to protect the human epidermis from UV light in the range from 280 to 400 nm, which formulation includes a cosmetically suitable carrier, together with compounds which absorb in the UV-B region and as photostable UV-A filters effective amounts of compounds of the formula I as defined in the specification.
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公开(公告)号:ES2088283T3
公开(公告)日:1996-08-01
申请号:ES93911483
申请日:1993-04-20
Applicant: BASF AG
Inventor: SCHADE CHRISTIAN , SANNER AXEL , WEKEL HANS-ULRICH , FROSCH FRANZ , WESTENFELDER HORST
IPC: A61K8/72 , A61K8/06 , A61K8/81 , C08F20/02 , C08F20/34 , C08F20/52 , C08F220/04 , C08F220/34 , C08F220/58 , C08F220/60 , C08F222/00 , C08F222/02 , C09K23/52 , A61K7/48
Abstract: A copolymer obtainable by free-radical polymerization ofA) 50-99.99% by weight of an olefinically unsaturated C3-C5 monocarboxylic acid, of an olefinically unsaturated C4-C8 dicarboxylic acid or the anhydride thereof or a mixture of such carboxylic acids or anhydrides withB) 0.01-50% by weight of an olefinically unsaturated quaternary ammonium compound of the formula I or II whereR1 is C6-C20-alkyl, C6-C20-alkenyl, C5-C8-cycloalkyl, phenyl, phenyl(C1-C12-alkyl) or (C1-C12-alkyl)phenyl,R2 is hydrogen, methyl or phenyl,R3 and R4 are each H or C1-C4-alkyl,X is halogen, C1-C4-alkoxysulfonyloxy or C1-C4-alkanesulfonate, it also being possible for the latter to occur as R3 or R4 with the formation of a betaine structure,Y is O or NH, andA is C1-C6-alkylene, or a mixture of such ammonium compounds,C) 0 to 49.99% by weight of an acrylate or methacrylate of the formula III where R1, R2 and Y have the abovementioned meanings, R5 is hydrogen, methyl or ethyl, and n is a number from 0 to 25,D) 0-49.99% by weight of other copolymerizable monomers andE) 0-5% by weight of one or more compounds with at least two olefinically unsaturated groups in the molecule as crosslinker. The copolymers are suitable as thickeners and dispersants, especially in cosmetic compositions.
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公开(公告)号:DE4213971A1
公开(公告)日:1993-11-04
申请号:DE4213971
申请日:1992-04-29
Applicant: BASF AG
Inventor: SCHADE CHRISTIAN DR , SANNER AXEL DR , WEKEL HANS-ULRICH DR , FROSCH FRANZ DR , WESTENFELDER HORST
IPC: A61K8/72 , A61K8/06 , A61K8/81 , C08F20/02 , C08F20/34 , C08F20/52 , C08F220/04 , C08F220/34 , C08F220/58 , C08F220/60 , C08F222/00 , C08F222/02 , C09K23/52 , C08F222/04 , C08F226/06 , B01F17/52 , A61K9/10
Abstract: A copolymer obtainable by free-radical polymerization ofA) 50-99.99% by weight of an olefinically unsaturated C3-C5 monocarboxylic acid, of an olefinically unsaturated C4-C8 dicarboxylic acid or the anhydride thereof or a mixture of such carboxylic acids or anhydrides withB) 0.01-50% by weight of an olefinically unsaturated quaternary ammonium compound of the formula I or II whereR1 is C6-C20-alkyl, C6-C20-alkenyl, C5-C8-cycloalkyl, phenyl, phenyl(C1-C12-alkyl) or (C1-C12-alkyl)phenyl,R2 is hydrogen, methyl or phenyl,R3 and R4 are each H or C1-C4-alkyl,X is halogen, C1-C4-alkoxysulfonyloxy or C1-C4-alkanesulfonate, it also being possible for the latter to occur as R3 or R4 with the formation of a betaine structure,Y is O or NH, andA is C1-C6-alkylene, or a mixture of such ammonium compounds,C) 0 to 49.99% by weight of an acrylate or methacrylate of the formula III where R1, R2 and Y have the abovementioned meanings, R5 is hydrogen, methyl or ethyl, and n is a number from 0 to 25,D) 0-49.99% by weight of other copolymerizable monomers andE) 0-5% by weight of one or more compounds with at least two olefinically unsaturated groups in the molecule as crosslinker. The copolymers are suitable as thickeners and dispersants, especially in cosmetic compositions.
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公开(公告)号:ES2272214T3
公开(公告)日:2007-05-01
申请号:ES00110272
申请日:2000-05-22
Applicant: BASF AG
Inventor: HABECK THORSTEN DR , PRECHTL FRANK DR , WUNSCH THOMAS DR , WESTENFELDER HORST
IPC: A61K8/49 , C07D233/64 , A61K8/00 , A61K8/02 , A61K8/06 , A61K47/22 , A61Q1/00 , A61Q1/04 , A61Q17/04 , C07D235/16 , C07D239/70 , C07D263/56 , C07D277/64 , C08K5/3447 , C08K5/35 , C08K5/47
Abstract: Empleo de compuestos de la fórmula I (Ver fórmula) en la que R1 y R2 son restos iguales o diferentes, electrófilos, elegidos entre el grupo constituido por ciano, alquilcarbonilo o arilcarbonilo, alquiloxicarbonilo o ariloxicarbonilo y aminocarbonilo, substituido en caso dado, R3 significa un átomo de hidrógeno, un resto alquilo con 1 hasta 20 átomos de carbono o un resto cicloalquilo con 3 hasta 20 átomos de carbono o un resto de la fórmula -CH2-CH2-SO3-M+, donde M+ significa un catión, X significa el resto divalente del oxígeno, del azufre o significa el resto (Ver fórmula) donde R3 tiene el significado anteriormente indicado, Z significa el resto divalente de las fórmulas II o III, que forman un sistema anillado con el resto de la fórmula I (Ver fórmula) pudiendo estar enlazado R4 una o varias veces sobre el anillo de bencilideno I o bien del anillo de naftilideno II, y significa hidrógeno, alquilo, cicloalquilo, alquiloxi, cicloalquiloxi, alcoxicarbonilo, monoalquilaminocarbonilo o dialquilaminocarbonilo, alquilamino, dialquilamino, todos ellos respectivamente con hasta 20 átomos de carbono, así como ciano, amino y SO3-M+, donde M+ significa un catión metálico, como filtros fotoestables para los UV en preparaciones cosméticas y farmacéuticas para la protección de la piel humana y del cabello humano contra las irradiaciones solares, solos o junto con compuestos absorbedores en el intervalo de los UV, en sí conocidos para las preparaciones cosméticas y farmacéuticas.
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公开(公告)号:ES2236776T3
公开(公告)日:2005-07-16
申请号:ES97117560
申请日:1997-10-10
Applicant: BASF AG
Inventor: SPERLING KARIN DR , WUNSCH THOMAS DR , WESTENFELDER HORST , TRENTMANN BEATE DR
IPC: C07D251/34 , A61K8/00 , A61K8/33 , A61K8/37 , A61K8/41 , A61K8/46 , A61K8/49 , A61Q1/00 , A61Q1/04 , A61Q5/00 , A61Q17/04 , A61K7/42
Abstract: LA PRESENTE INVENCION TRATA DE AGENTES COSMETICOS QUE CONTIENEN UNA COMBINACION DE FILTROS FOTOPROTECTORES DE FORMULA, ADEMAS DE OTROS FILTROS FOTOPROTECTORES.
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