公开(公告)号：US09393589B2

公开(公告)日：2016-07-19

申请号：US13967770

申请日：2013-08-15

Applicant: Eastman Chemical Company

Inventor： David Olmeijer ,  J. Wallace Parce ,  Benjamin Wang ,  Kevin Krogman

IPC: B05D5/12 ,  B05D7/02 ,  B05D1/18 ,  B05D1/02 ,  B05D1/20 ,  B05D3/00 ,  B05D3/10 ,  B05D7/00 ,  B05D1/36 ,  C08J7/04 ,  C09D183/00 ,  C08F10/00 ,  C08F18/14 ,  C08F220/32 ,  C09D133/14

CPC classification number: B05D1/185 ,  B05D1/02 ,  B05D1/204 ,  B05D1/208 ,  B05D1/36 ,  B05D3/007 ,  B05D3/107 ,  B05D7/54 ,  B05D7/56 ,  B05D7/58 ,  B05D2350/35 ,  B05D2518/10 ,  C08F18/14 ,  C08F220/32 ,  C08F2220/325 ,  C08F2230/085 ,  C09D133/14 ,  Y10S977/882 ,  Y10S977/883 ,  Y10S977/895 ,  Y10S977/896 ,  Y10S977/897 ,  Y10T428/31511 ,  Y10T428/31663 ,  Y10T428/31938 ,  C08F220/34 ,  C08F220/18

Abstract: The invention provides materials and methods for forming coatings on substrates. The coatings are durable and resistant to damage from environmental, chemical, thermal, and/or radiative sources. In some embodiments, the coatings comprise bilayers of electrostatically charged materials. The bilayers are created by alternately applying solutions comprising water-soluble, electrostatically charged materials. Durability is imparted to the coatings by the formation of crosslinks that are formed within and between layers after deposition of the coatings.

Abstract translation: 本发明提供了在基材上形成涂层的材料和方法。 涂层是耐用的，并且能够抵抗环境，化学，热和/或辐射源的损坏。 在一些实施方案中，涂层包含静电荷材料的双层。 双层是通过交替施加包含水溶性静电填充材料的溶液而产生的。 通过在沉积涂层之后在层内和层之间形成交联，赋予涂层耐久性。

公开(公告)号：US07779883B2

公开(公告)日：2010-08-24

申请号：US11468711

申请日：2006-08-30

Applicant: Ya-Hong Xie

Inventor： Ya-Hong Xie

IPC: B32B37/00

CPC classification number: B05D3/0218 ,  B05D1/185 ,  B05D1/208 ,  B05D3/0254 ,  B05D3/10 ,  B82Y30/00 ,  B82Y40/00 ,  G03F7/0002 ,  Y10T156/17

Abstract: A device for forming a self-assembled film on a substrate containing a film precursor includes a first heating member and a second heating member disposed adjacent to the first heating member, the second heating member being separated from the first heating member by a gap. The device includes a movable pusher member configured for advancing the substrate from the first heating member to the second heating member.

Abstract translation: 在含有膜前体的基板上形成自组装膜的装置包括：第一加热部件和与第一加热部件相邻配置的第二加热部件，第二加热部件与第一加热部件间隔开。 该装置包括可移动推动器构件，其构造成将基板从第一加热构件推进到第二加热构件。

公开(公告)号：US5962079A

公开(公告)日：1999-10-05

申请号：US778296

申请日：1997-01-02

Applicant: Jeffrey T. Koberstein ,  Christopher L. Mirley

Inventor： Jeffrey T. Koberstein ,  Christopher L. Mirley

IPC: B05D1/20 ,  B05D3/04 ,  B05D3/06 ,  C08F2/48

CPC classification number: B05D3/067 ,  B05D1/208 ,  B05D3/046 ,  B82Y10/00 ,  B82Y30/00 ,  B82Y40/00 ,  Y10S438/939

Abstract: Ultra thin organo-ceramic and metal oxide films are prepared under room temperature and atmospheric conditions by exposing .alpha., .omega.--functional siloxane oligomers and fatty acid metal soaps, respectively, to a combination of ultraviolet light (UV) and ozone (O.sub.3). The process includes the steps of preparing ultra thin .alpha., .omega.--functional polysiloxane and fatty acid metal soap films using, but not limited to, the Langmuir-Blodgett (LB) technique. The LB technique permits construction of molecular monolayer or multilayer films on a variety of substrates. By using carboxylic acid end groups on the siloxane oligomers, metal ions can be incorporated into the SiO.sub.x film after UV-ozone exposure. This technique can be used to make electronically, optically, and chemically important organo-ceramic and metal oxide films on temperature sensitive substrates.

Abstract translation: 通过将α，ω-官能的硅氧烷低聚物和脂肪酸金属皂分别暴露于紫外线（UV）和臭氧（O3）的组合，在室温和大气条件下制备超薄的有机陶瓷和金属氧化物膜。 该方法包括使用但不限于Langmuir-Blodgett（LB）技术制备超薄α，ω-官能聚硅氧烷和脂肪酸金属皂膜的步骤。 LB技术允许在各种基底上构建分子单层或多层膜。 通过在硅氧烷低聚物上使用羧酸端基，可以在UV-臭氧暴露后将金属离子掺入到SiOx膜中。 该技术可用于在温度敏感的基材上制造电子，光学和化学重要的有机陶瓷和金属氧化物膜。

公开(公告)号：US5405656A

公开(公告)日：1995-04-11

申请号：US161063

申请日：1993-12-03

Applicant: Futoshi Ishikawa ,  Koji Kondo ,  Masahiro Irie

Inventor： Futoshi Ishikawa ,  Koji Kondo ,  Masahiro Irie

IPC: B01J23/44 ,  B01J37/02 ,  B01J37/08 ,  B01J37/34 ,  B05D1/20 ,  C23C18/16 ,  C23C18/30 ,  H05K3/18 ,  B05D1/18 ,  B05D3/06

CPC classification number: B82Y30/00 ,  B01J23/44 ,  B01J37/0203 ,  B01J37/086 ,  B01J37/344 ,  B01J37/348 ,  B01J37/349 ,  B05D1/202 ,  B05D1/208 ,  B82Y40/00 ,  C23C18/1608 ,  C23C18/1612 ,  C23C18/182 ,  C23C18/1831 ,  C23C18/1868 ,  C23C18/1879 ,  C23C18/204 ,  C23C18/30 ,  H05K3/185

Abstract: The present invention relates to a solution for catalytic treatment, which is effective for applying a catalyst-metal onto the surface of a substrate, which can provide a film having excellent properties such as adhesion, precision and selectivity through electroless plating or the like, and which does not cause a premature and undesirable decomposition in a bath. The solution for catalytic treatment comprises a catalyst-metal in the form of ions, which permits the deposition of the metal serving as a catalyst on a substrate by applying the solution onto the surface of the substrate and then irradiating the substrate with light rays. The present invention also relates to a method of applying a catalyst onto a substrate and a method of forming an electrical conductor in which such a solution for catalytic treatment is employed.

Abstract translation: 本发明涉及一种用于催化处理的溶液，其有效地将催化剂金属施加到基材表面上，其可以通过无电镀等提供具有优异性能如粘合性，精度和选择性的膜，以及 这不会在浴中引起过早和不期望的分解。 用于催化处理的溶液包括离子形式的催化剂金属，其允许通过将溶液施加到基材的表面上然后用光线照射基板，将用作催化剂的金属沉积在基材上。 本发明还涉及将催化剂施加到基材上的方法以及形成其中使用这种催化处理溶液的电导体的方法。

公开(公告)号：US5273788A

公开(公告)日：1993-12-28

申请号：US916384

申请日：1992-07-20

Applicant: Bing-Kun Yu

Inventor： Bing-Kun Yu

IPC: B05D1/20 ,  B05D3/06 ,  B01J3/06

CPC classification number: B82Y30/00 ,  B05D1/208 ,  B82Y40/00

Abstract: A layer of a hydrocarbon molecule is applied to a substrate by the Langmuir-Blodgett technique, and the surface is irradiated with a laser to decompose the layer of molecules at the surface without influencing the substrate. After decomposition the carbon atoms rearrange on the surface of the substrate to form a DLC film. The method of the invention may also be used to form other film, using a suitable molecule to produce the LB layer before irradiation.

Abstract translation: 通过Langmuir-Blodgett技术将一层烃分子施加到基底上，并用激光照射表面以在表面分解分子层而不影响底物。 分解后，碳原子在衬底表面上重排形成DLC膜。 本发明的方法也可用于形成其它膜，使用合适的分子在照射前产生LB层。

公开(公告)号：US12011736B2

公开(公告)日：2024-06-18

申请号：US17558996

申请日：2021-12-22

Applicant: The Board of Trustees of the University of Illinois

Inventor： Dane Sievers ,  Sartaj Grewal ,  Lukas Janavicius ,  Julian Michaels

IPC: B05D1/20 ,  B05C3/05 ,  B05C11/02 ,  B05C11/11 ,  B82Y40/00 ,  C09D125/06 ,  B82Y30/00

CPC classification number: B05D1/204 ,  B05C3/05 ,  B05C11/028 ,  B05C11/11 ,  B05D1/208 ,  C09D125/06 ,  B82Y30/00 ,  B82Y40/00

Abstract: In an example, a method including dispensing a liquid onto a first portion of a surface of a substrate and dispensing a solution comprising colloidal spheres onto a second portion of the surface of the substrate. The method additionally includes agitating the colloidal spheres to disperse the colloidal spheres along the first portion and the second portion of the surface of the substrate and directing air flow above the colloidal spheres inducing rotation of the colloidal spheres. In another example, a method includes positioning a retaining ring on a surface of a liquid above a substrate below the surface of the liquid and dispensing a solution comprising colloidal spheres onto the surface of the liquid within a surface area of the retaining ring. The method further includes agitating the surface of the liquid and the colloidal spheres to disperse the colloidal spheres along the surface area of the retaining ring.

公开(公告)号：US07118784B1

公开(公告)日：2006-10-10

申请号：US11168266

申请日：2005-06-27

Applicant: Ya-Hong Xie

Inventor： Ya-Hong Xie

IPC: B05D3/02

CPC classification number: B05D3/0218 ,  B05D1/185 ,  B05D1/208 ,  B05D3/0254 ,  B05D3/10 ,  B82Y30/00 ,  B82Y40/00 ,  G03F7/0002 ,  Y10T156/17

Abstract: A method of forming a self-assembled film with periodic nanometer dimension features (e.g., holes) on a substrate includes the steps of providing film precursors on the substrate, wherein the film precursors are maintained in an amorphous state. Where the film precursors are block copolymers, a heating member is provided. The substrate and the heating member are then moved relative to one another so as to raise the temperature of a portion of the film precursor on the substrate above its glass transition temperature. Relative movement between the substrate and heating member continues until a self-assembled crystalline film is formed over the surface of the substrate. In an alternative embodiment, a pH dispensing member is provided to dispense a pH adjusting agent onto the substrate that promotes self-assembly of a crystalline film.

Abstract translation: 在衬底上形成具有周期性纳米尺寸特征（例如，孔）的自组装膜的方法包括在衬底上提供膜前体的步骤，其中膜前体保持在非晶状态。 当膜前体是嵌段共聚物时，提供加热构件。 然后使衬底和加热构件相对于彼此移动，以便将衬底上的膜前体的一部分的温度升高到其玻璃化转变温度以上。 基板和加热部件之间的相对运动继续进行，直到在基板的表面上形成自组装的晶体膜。 在替代实施例中，提供pH分配构件以将pH调节剂分配到促进结晶膜自组装的衬底上。

公开(公告)号：US5766784A

公开(公告)日：1998-06-16

申请号：US630022

申请日：1996-04-08

Applicant: Suresh Baskaran ,  Gordon L. Graff ,  Lin Song

Inventor： Suresh Baskaran ,  Gordon L. Graff ,  Lin Song

IPC: B05D1/18 ,  B05D1/20 ,  C01G23/047 ,  C23C18/12

CPC classification number: C23C18/1216 ,  B05D1/185 ,  B82Y30/00 ,  B82Y40/00 ,  C01G23/047 ,  B05D1/208 ,  C01P2002/70 ,  C01P2002/84 ,  C01P2004/03 ,  C01P2004/86

Abstract: The invention provides a method for synthesizing a titanium oxide-containing film comprising the following steps: (a) preparing an aqueous solution of a titanium chelate with a titanium molarity in the range of 0.01M to 0.6M. (b) immersing a substrate in the prepared solution, (c) decomposing the titanium chelate to deposit a film on the substrate. The titanium chelate maybe decomposed acid, base, temperature or other means. A preferred method provides for the deposit of adherent titanium oxide films from C2 to C5 hydroxy carboxylic acids. In another aspect the invention is a novel article of manufacture having a titanium coating which protects the substrate against ultraviolet damage. In another aspect the invention provides novel semipermeable gas separation membranes, and a method for producing them.

Abstract translation: 本发明提供一种合成含氧化钛膜的方法，包括以下步骤：（a）制备钛摩尔浓度为0.01M至0.6M范围内的钛螯合物水溶液。 （b）将基材浸入制备的溶液中，（c）分解钛螯合物以在基材上沉积膜。 钛螯合物可以分解酸，碱，温度等手段。 优选的方法提供从C2到C5羟基羧酸沉积粘附的氧化钛膜。 在另一方面，本发明是具有钛涂层的新型制造品，其保护基底免受紫外线损伤。 另一方面，本发明提供新型的半透气分离膜及其制造方法。

公开(公告)号：US5661092A

公开(公告)日：1997-08-26

申请号：US522948

申请日：1995-09-01

Applicant: Jeffrey T. Koberstein ,  Christopher L. Mirley

Inventor： Jeffrey T. Koberstein ,  Christopher L. Mirley

IPC: B05D1/20 ,  B05D3/04 ,  B05D3/06 ,  C08F2/48 ,  H01L21/306

CPC classification number: B05D3/067 ,  B05D1/208 ,  B05D3/046 ,  B82Y10/00 ,  B82Y30/00 ,  B82Y40/00 ,  Y10S438/939

Abstract: Ultra thin organo-ceramic and metal oxide films are prepared under room temperature and atmospheric conditions by exposing .alpha.,.omega.-functional siloxane oligomers and fatty acid metal soaps, respectively, to a combination of ultraviolet light (UV) and ozone (O.sub.3). The process includes the steps of preparing ultra thin .alpha.,.omega.-functional polysiloxane and fatty acid metal soap films using, but not limited to, the Langmuir-Blodgett (LB) technique. The LB technique permits construction of molecular monolayer or multilayer films on a variety of substrates. By using carboxylic acid end groups on the siloxane oligomers, metal ions can be incorporated into the SiOx film after UV-ozone exposure. This technique can be used to make electronically, optically, and chemically important organo-ceramic and metal oxide films on temperature sensitive substrates.

Abstract translation: 通过将α，ω-官能的硅氧烷低聚物和脂肪酸金属皂分别暴露于紫外线（UV）和臭氧（O3）的组合，在室温和大气条件下制备超薄的有机陶瓷和金属氧化物膜。 该方法包括使用但不限于Langmuir-Blodgett（LB）技术制备超薄α，ω-官能聚硅氧烷和脂肪酸金属皂膜的步骤。 LB技术允许在各种基底上构建分子单层或多层膜。 通过在硅氧烷低聚物上使用羧酸端基，可以在UV-臭氧暴露后将金属离子掺入到SiOx膜中。 该技术可用于在温度敏感的基材上制造电子，光学和化学重要的有机陶瓷和金属氧化物膜。

公开(公告)号：US09492841B2

公开(公告)日：2016-11-15

申请号：US13847457

申请日：2013-03-19

Applicant: IMEC ,  St. Petersburg Electrotechnical University

Inventor： Victor Luchinin ,  Svetlana Goloudina ,  Vyacheslav Pasyuta ,  Alexey Ivanov ,  Mikhail Baklanov ,  Mikhail Krishtab

IPC: B05D1/20 ,  B32B37/15 ,  B32B18/00 ,  B32B27/04 ,  B32B27/28 ,  H05K1/03 ,  H01L21/02 ,  H05K3/14 ,  C09D179/08 ,  C08G73/10

CPC classification number: B32B37/15 ,  B05D1/20 ,  B05D1/208 ,  B32B18/00 ,  B32B27/04 ,  B32B27/281 ,  B32B2260/046 ,  B32B2305/026 ,  B32B2305/07 ,  B32B2307/00 ,  B32B2307/204 ,  B32B2379/08 ,  B32B2457/00 ,  C08G73/1067 ,  C09D179/08 ,  H01L21/02285 ,  H01L21/02318 ,  H05K1/03 ,  H05K3/143 ,  H05K2201/01 ,  H05K2201/0104 ,  H05K2201/0116 ,  H05K2201/0154 ,  H05K2201/0162 ,  Y10T428/249979 ,  Y10T428/249991 ,  C08K5/175

Abstract: Method for pore sealing a porous substrate, comprising: forming a continuous monolayer of a polyimide precursor on a liquid surface, transferring said polyimide precursor monolayer onto the porous substrate with the Langmuir-Blodgett technique, and imidization of the transferred polyimide precursor monolayers, thereby forming a polyimide sealing layer on the porous substrate. Porous substrate having at least one surface on which a sealing layer is provided to seal pores of the substrate, wherein the sealing layer is a polyimide having a thickness of a few monolayers and wherein there is no penetration of the polyimide into the pores.

Abstract translation: 用于孔密封多孔基材的方法，包括：在液体表面上形成聚酰亚胺前体的连续单层，使用Langmuir-Blodgett技术将所述聚酰亚胺前体单层转移到多孔基材上，并将转移的聚酰亚胺前体单层酰亚胺化，从而形成 多孔基材上的聚酰亚胺密封层。 具有至少一个表面的多孔基材，其上设有密封层以密封基材的孔，其中密封层是具有几个单层厚度的聚酰亚胺，并且其中聚酰亚胺不渗透到孔中。