12.
    发明专利
    未知

    公开(公告)号:DE59506644D1

    公开(公告)日:1999-09-23

    申请号:DE59506644

    申请日:1995-03-11

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP95/00912 Sec. 371 Date Oct. 24, 1996 Sec. 102(e) Date Oct. 24, 1996 PCT Filed Mar. 3, 1995 PCT Pub. No. WO95/25759 PCT Pub. Date Sep. 28, 1995Graft polymers which contain N-vinyl units and in which the grafting base is a polymer which contains in each case at least 5% by weight of units of the formulae (I) (II) where R1 and R2 are each H or C1-C6-alkyl, monoethylenically unsaturated monomers are grafted onto the grafting base in a weight ratio of from 100:1 to 1:100, and which have K values of at least 7 (determined according to H. Fikentscher in 5% strength by weight aqueous solution at 25 DEG C. and pH 7), are prepared by polymerization of monoethylenically unsaturated monomers in the presence of polymers which in each case contain at least 5% by weight of units of the formulae I and/or II as the grafting base in a weight ratio of from 100:1 to 1:100, and are used as dispersants for pigments, as additives for detergents and cleaning agents, and strength agents for paper and as soil stabilizers and for fertilizer compaction.

    13.
    发明专利
    未知

    公开(公告)号:DE59504710D1

    公开(公告)日:1999-02-18

    申请号:DE59504710

    申请日:1995-03-10

    Applicant: BASF AG

    Abstract: Method of modifying cleaned or chemically pre-treated metal surfaces with aq. solns. of organic polymers contg. amino gps. In an example, a sample of Mn-modified, low Zn content, phosphatised steel that had been cleaned with water was immersed for 60s in a 0.1 wt.% aq. polyvinylamine soln. at 50 deg.C, then after drying in air the sample was immersed for 5s in deionised water and then after drying in air again the sample was cathodically electro-plated in a bath according to the comparative example in German patent application DE4208056-A2. The sample was plated at 320-380 V to give a 23 micron thick coating, and then fired for 25 mins. at 165 deg.C. A 0.1 mm wide incision was made in the lacquered sample, extending down to the metal surface and the sample was sprayed for 15 days with aq. NaCl soln. (5 wt.%) at 40 deg.C (salt water spray test), whilst another sample was immersed for 10 days in an aq. NaCl soln. (5 wt.%) warmed to 55 deg.C (salt water soak test). No rust was observed for the soak test, whilst only a slight amt. of rust was observed for the spray test.

    16.
    发明专利
    未知

    公开(公告)号:ES2111895T3

    公开(公告)日:1998-03-16

    申请号:ES94900129

    申请日:1993-11-11

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP93/03159 Sec. 371 Date May 22, 1995 Sec. 102(e) Date May 22, 1995 PCT Filed Nov. 11, 1993 PCT Pub. No. WO94/12571 PCT Pub. Date Jun. 9, 1994Mixtures of (I) polymers of monoethylenically unsaturated dicarboxylic acids having a molecular weight of from 200 to 5,000 and (II) (1) copolymers having a molecular weight of from 10,000 to 150,000 and comprising (a) from 10 to 70% by weight of monoethylenically unsaturated C4-C8-dicarboxylic acids or the salts thereof and (b) from 30 to 90% by weight of monoethylenically unsaturated C3-C10-monocarboxylic acids and/or the salts thereof, (2) graft polymers having a molecular weight of from 5,000 to 150,000, which are obtainable by free radical graft polymerization of (A) monoethylenically unsaturated C3-C10-carboxylic acids or the anhydrides and/or the salts thereof in the presence of (B) mono-, oligo- or polysaccharides and the derivatives thereof in a weight ratio (A) : (B) of (95 to 20) : (5 to 80), and/or (3) polyaminocarboxylic acids and/or polymers containing aminocarboxylic acid groups contain the components (I) and (II) in a weight ratio of from 10 : 0.5 to 0.5 : 10 and are used as additives for phosphate-free or low-phosphate textile detergents or as dispersants or coating inhibitors in cleaners for hard surfaces.

    SOLUCIONES O DISPERSIONES ACUOSAS DE COPOLIMERIZADOS.

    公开(公告)号:MX9602940A

    公开(公告)日:1997-12-31

    申请号:MX9602940

    申请日:1995-01-16

    Applicant: BASF AG

    Abstract: Soluciones o dispersiones acuosas de copolimerizados, que se obtienen por copolimerizacion iniciada por radicales libres de A1) 40 hasta 60% en mol de monoolefinas con 6 hasta 40 átomos de carbono o alquil vinil éteres con 6 hasta 40 átomos de carbono o mezclas a partir de alquil vinil éteres con 6 hasta 40átomos de carbono y hasta 50% en mol, con respecto a la cantidad total del componente A1, de monoolefinas con 6 hasta 40 átomos de carbono, con B1) 60 hasta 40% en mol de anhídridos de ácidos dicarboxilicos monoetilénicamente insaturados con 4 hasta 8 átomos de carbono o por copolimerizacion iniciada por radicales libres de A2) 50 hasta 90% en peso de acrilato o metacrilatos de alquilo con 6 hasta 40 átomos de carbono o vinil ésteres de ácidos carboxílicos con 6 hasta 40 átomos de carbono, o mezclas de los mismos, con B2) 10 hasta 50% en peso de ácidos carboxílicos monoetilénicamente insaturados con 3 hasta 12 átomos de carbono, anhídridos de ácidos dicarboxílicos monoetilénicamente insaturados con 4 hasta 12 átomos de carbono, semiésteres o semiamidas de ácidos dicarboxílicos monoetilénicamente insaturados con 4 hasta 12 átomos de carbono, amidas de ácidos carboxílicos monoetilénicamente insaturados con 3 hasta 12 átomos de carbono, o mezclas de los mismos dando copolimerizados con masas molares de 500 hasta 30 000, estando los grupos carboxilo presentes en el medio acuoso al menos parcialmente neutralizados y pudiendo una parte de los grupos carboxilo estar presentes en forma amida, cuyas soluciones o dispersiones acuosas están caracterizadas por contener 0.5 hasta 40% en peso, con respecto a la cantidad de copolimerizado, de emulsionantes. Estas soluciones o dispersiones acuosas son apropiadas para el engrase y relleno de cueros y pieles.

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