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    31.
    发明专利
    未知

    公开(公告)号：DE19506557A1

    公开(公告)日：1996-08-29

    申请号：DE19506557

    申请日：1995-02-24

    Applicant: BASF AG

    Inventor： FISCHER DAVID DR ,  LANGHAUSER FRANZ DR ,  SCHWEIER GUENTHER DR ,  BRINTZINGER HANS-HERBERT PROF ,  LEYSER NADINE

    IPC: B01J31/22 ,  C07F9/54 ,  C07F17/00 ,  C08F4/619 ,  C08F4/6192 ,  C08F4/642 ,  C08F10/00 ,  C07C19/00 ,  C07F9/6568 ,  C07F7/00 ,  C07F9/50 ,  C07F9/70 ,  C07F9/90 ,  C07C211/62 ,  C08F4/42

    Abstract: The invention relates to metallocene complexes of the general formula (I), wherein: M is a metal from subgroups III, IV, V or VI of the periodic table of elements or a metal from the lanthanides; X is fluorine, chlorine, bromine, iodine, hydrogen, C1-C10 alkyl, C6-C15 aryl or -OR , wherein R is C1-C10 alkyl, C6-C15 aryl, alkyl aryl, aryl alkyl, alkyl fluoride or aryl fluoride with, respectively, 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical; R to R and R to R are hydrogen, C1-C10 alkyl, 5- to 7-membered cycloalkyl, which in turn can carry C1-C10 alkyls as substituents, C6-C15 aryl or aryl alkyl, wherein two adjacent radicals may together stand for cyclic groups containing 4 to 15 C atoms, or Si(R )3 with R being C1-C10 alkyl, C6-C15 aryl or C3-C10 cycloalkyl; Y is nitrogen, phosphorous, arsenic, antimony or bismuth; R , R are hydrogen, C1-C10 alkyl, C3-C10 cycloalkyl or C6-C15 aryl; n is 0, 1 or 2; and Z stands for halogenides, carboxylates, monosubstituted sulfonates, borates or alcoholates. The invention also relates to ligand systems of the general formula (II) as intermediates.

    33.
    发明专利
    未知

    公开(公告)号：DE4431838A1

    公开(公告)日：1996-03-14

    申请号：DE4431838

    申请日：1994-09-07

    Applicant: BASF AG

    Inventor： LYNCH JOHN DR ,  FISCHER DAVID DR ,  LANGHAUSER FRANZ DR ,  GOERTZ HANS-HELMUT DR ,  KERTH JUERGEN DR ,  SCHWEIER GUENTHER DR

    IPC: C07F17/00 ,  C08F4/60 ,  C08F4/623 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/64 ,  C08F4/642 ,  C08F4/646 ,  C08F4/655 ,  C08F4/68 ,  C08F10/00

    Abstract: Supported metallocene catalysts are claimed which are obtd. by (a) depositing a mixt. of (A) a metallocene complex(es) of formula (I) and (B) a metal cpd(s). of formula (II) on a support which is opt. pretreated with a metal cpd(s). of formula (III); and (b) activating the system by reacting with a soln. or suspension of a cpd. which forms metallocenium ions. M )m(X )o (II) M )p(X )q (III) M = Ti, Zr, Hf, V, Nb or Ta; X = F, Cl, Br, I, H, 1-10C alkyl, 6-15C aryl or OR ; R = 1-10C alkyl, 6-15C aryl or alkaryl, aralkyl, fluoroalkyl or fluoroaryl with 1-10C alkyl and 6-20C aryl gps.; R -R = H, 1-10C alkyl, 5-7C cycloalkyl (opt. substd. with 1-10C alkyl), or 6-15C aryl or aralkyl, opt. with 2 adjacent gps. forming a 4-15C ring or Si(R )3; R = 1-10C alkyl, 6-15C aryl or 3-10C cycloalkyl; Y = Si, Ge, Sn or C; R = H, 1-10C alkyl, 3-10C cycloalkyl or 6-15C aryl; n = 1, 2, 3 or 43; E = -O-, -S-, -NR - or -PR -; R = 1-10C alkyl, 3-10C cycloalkyl, 6-15C aryl, alkaryl or Si(R )3; R = 1-10C alkyl, 8-10C cycloalkyl, 6-15C aryl or alkaryl; M = alkali, alkaline earth or Gp.III metal; R = as for R (except for F-substd. gps.); X = F, Cl, Br or I; m = 1-3; o = 0-2; m+o = valency of M ; M = as for M , R = as for R ; X = F, Cl, Br or I; p = 1-3; q = 0-2; and p+q = valency of M . Also claimed are (i) the process as above, and (ii) the prodn. of polyolefins at -60 to +200 degrees C and 0.5-3500 bar in the presence of the above catalyst system, which is activated before, during or after its addn. to the reactor.

    Cyclopentadienes containing functionalised hydrocarbon side chains
    36.
    发明专利
    Cyclopentadienes containing functionalised hydrocarbon side chains 未知

    公开(公告)号：DE4303647A1

    公开(公告)日：1994-08-11

    申请号：DE4303647

    申请日：1993-02-09

    Applicant: BASF AG

    Inventor： LANGHAUSER FRANZ DR ,  SCHLUND RUEGER DR ,  LUX MARTIN DR ,  JUTZI PETER PROF DR ,  DAHLHAUS JUERGEN

    IPC: C07C17/263 ,  C07C22/02 ,  C07C43/162 ,  C07C211/25 ,  C07C321/10 ,  C07C321/20

    Abstract: Cyclopentadienes of the general formulae Ia to Ie in which the substituents and indices have the following meaning: R , R , R and R are C1- to C5-alkyl groups or C6- to C 15-aryl groups, X is NR R , OR , SR , Cl, Br or I, where R and R are hydrogen, C1- to C5-alkyl groups or C6- to C15-aryl groups and n is an integer from 2 to 5, and process for the preparation of cyclopentadienes of the general formulae IIa to IIe in which the substituents and indices have the following meaning: R , R , R and R are C1- to C5-alkyl groups or C6- to C 15-aryl groups, X is NR R , OR , SR , Cl, Br or I, where R and R are hydrogen, C1- to C5-alkyl groups or C6- to C15-aryl groups and m is an integer from 1 to 5, where in a first step lithium compounds of the general formula IIIa or IIIb or mixtures thereof and IIIc or IIId or mixtures thereof are converted with carboxylic acid esters of the general formula IV X(CH2)mCOOR in which R is a C1- to C4-alkyl group to dienols of the general formulae Va to Vd and the dienols of the general formulae Va to Vd are then converted by acid-catalysed ring closure to the cyclopentadienes of the general formulae IIa to IIe.

    38.
    发明专利
    未知

    公开(公告)号：DE59407909D1

    公开(公告)日：1999-04-15

    申请号：DE59407909

    申请日：1994-10-20

    Applicant: BASF AG

    Inventor： LANGHAUSER FRANZ DR ,  KERTH JUERGEN DR ,  SCHWEIER GUENTHER DR ,  BRINTZINGER HANS-HERBERT PROF ,  MANSEL STEFAN

    IPC: C07C22/02 ,  C07F7/08 ,  C07F17/00 ,  C08F4/6192 ,  C08F4/622 ,  C08F4/6392 ,  C08F4/642 ,  C08F4/646 ,  C08F4/68 ,  C08F10/00

    Abstract: Metallocene complexes of the general formula I in which the substituents have the following meaning: M is titanium, zirconium, hafnium, vanadium, niobium or tantalum, X is fluorine, chlorine, bromine, iodine, hydrogen, C1- to C10-alkyl, C6- to C15-aryl or -OR , where R is C1- to C10-alkyl, C6- to C15-aryl, alkylaryl, arylalkyl, fluoroalkyl or fluoroaryl in each case having 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical, R to R are hydrogen, C1- to C10-alkyl, 5- to 7-membered cycloalkyl which for its part can carry C1- to C10-alkyls as substituents, C6- to C15-aryl or arylalkyl, where, if appropriate, two adjacent radicals together can also stand for cyclic groups having 4 to 15 C atoms, or Si(R )3 where R is C1- to C10-alkyl, C6- to C15-aryl or C3- to C10-cycloalkyl, Z is silicon, germanium, tin or carbon, Y and Y are where R to R are hydrogen, C1- to C10-alkyl, 5- to 7-membered cycloalkyl which for its part can carry C1- to C10-alkyls as substituents, C6- to C15-aryl or arylalkyl, where, if appropriate, two adjacent radicals together can also stand for cyclic groups having 4 to 15 C atoms, or Si(R )3, where R is C1- to C10-alkyl, C6- to C15-aryl or C3- to C10-cycloalkyl, and u, v and w are integers from 0 to 7, with the proviso that the sum u + v + w >/= 2, and cyclopentadienyl compounds of the general formula II and cyclopentadienyl compounds of the general formula III as intermediates.t

    39.
    发明专利
    未知

    公开(公告)号：DE19726796A1

    公开(公告)日：1999-01-07

    申请号：DE19726796

    申请日：1997-06-24

    Applicant: BASF AG

    Inventor： HUEFFER STEPHAN DR ,  ROESCH JOACHIM DR ,  LANGHAUSER FRANZ DR ,  LILGE DIETER DR ,  HINGMANN ROLAND DR

    IPC: C08J5/18 ,  C08F4/02 ,  C08F4/646 ,  C08F6/04 ,  C08F10/00 ,  C08F10/06 ,  C08F210/16 ,  C08L23/10 ,  C08L23/12 ,  C08L23/14 ,  D01F6/06 ,  D01F6/30 ,  C08F210/06

    Abstract: Propylene polymers (I) contain a matrix of propylene homopolymer and a copolymer of propylene and other alkenes. The novelty is that the polymers satisfy certain condition(s) when separated by tacticity and comonomer distribution of the polymer chain. They are first dissolved in boiling xylene, then the solution is cooled to 25 degrees C at a rate of 10 degrees C/hour. The polymers are separated, into fractions of different solubility at increasing temperature, whilst the matrix remains undissolved on heating the cooled solution to 80 degrees C. The conditions are that the amount of matrix remaining undissolved on further heating is (i) > 20 wt.% at 112 degrees C; (ii) > 8 wt.% at 117 degrees C and/or > 1 wt.% at 122 degrees C. Also claimed are (1) a method of producing (I); and (2) films, fibres or mouldings made from (I).

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